Forced hydrolysis of FeCl3 solutions in the presence of Cr3+ ions in acidic medium (CROSBI ID 708600)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | domaća recenzija
Podaci o odgovornosti
Robić, Marko ; Ristić, Mira ; Kuzmann, Erno ; Homonnay, Zoltan ; Krehula, Stjepko ; Musić, Svetozar
engleski
Forced hydrolysis of FeCl3 solutions in the presence of Cr3+ ions in acidic medium
Forced hydrolyses of FeCl3 solutions in the presence of Cr3+ ions without alkali addition were investigated at 200°C. These precipitation systems were compared to corresponding reference systems. The isolated precipitates were characterized with XRD, 57Fe Mössbauer, FT-IR, FE SEM and photocatalytic measurements. Although chromium was not detected by EDS (Energy Dispersive X-ray Spectroscopy), the analysis of samples precipitated in the presence of Cr3+ ions showed several effects which can be attributed to the presence of these ions in the starting solutions. Autoclaving of FeCl3 solutions in the presence of Cr3+ impeded the transformation kinetics -FeOOH to a-Fe2O3. Relative intensities of prominent diffraction lines 104 and 110 of a-Fe2O3 changed as a result of the presence of Cr3+ ions. Changes in the size and formation of lemon-like particles instead of cube-like a-Fe2O3 particles were also noticed. The presence of Cr3+ ions in hydrolysing FeCl3 solution influenced the photocatalytic degradation of rhodamine B. Since no specific adsorption of Cr3+ ions occurred in the acidic pH medium, it was inferred that traces of Cr3+ ions enter into the structural tunnels of b-FeOOH crystals. It can be assumed that a-Fe2O3 crystals start to grow on very fine and thin b-FeOOH crystallites which were not completely dissolved, but were previously affected by Cr3+ ions.
forced hydrolysis ; hematite
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
Podaci o prilogu
378-379.
2021.
objavljeno
Podaci o matičnoj publikaciji
Barišić, Dajana
Zagreb: Prirodoslovno-matematički fakultet Sveučilišta u Zagrebu
978-953-6076-90-1
Podaci o skupu
5. Simpozij studenata doktorskih studija PMF-a = 5th Faculty of Science PhD Student Symposium
poster
24.04.2021-25.04.2021
Zagreb, Hrvatska