engleski

Role of substituents in Hofmann-Löffler-Freytag cyclization of biomolecules. A quantum chemical study

N-centered radicals in model di-peptides can rearrange to the corresponding C-, O-, and S- centered radicals on peptide side chains. Produced 5-membered heterocyclic products can be markers of the oxidative damage inside cells.

N-centered radicals, Radical rearrangement, Radical stability

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