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Pregled bibliografske jedinice broj: 1140754

Alcohol Oxidation Assisted by Molybdenum Hydrazonato Catalysts Employing Hydroperoxide Oxidants


Mihalinec, Josipa; Pajski, Matea; Guillo, Pascal; Mandarić, Mirna; Bebić, Nikol; Pisk, Jana; Vrdoljak, Višnja
Alcohol Oxidation Assisted by Molybdenum Hydrazonato Catalysts Employing Hydroperoxide Oxidants // Catalysts, 11 (2021), 8; 881, 14 doi:10.3390/catal11080881 (međunarodna recenzija, članak, znanstveni)


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Naslov
Alcohol Oxidation Assisted by Molybdenum Hydrazonato Catalysts Employing Hydroperoxide Oxidants

Autori
Mihalinec, Josipa ; Pajski, Matea ; Guillo, Pascal ; Mandarić, Mirna ; Bebić, Nikol ; Pisk, Jana ; Vrdoljak, Višnja

Izvornik
Catalysts (2073-4344) 11 (2021), 8; 881, 14

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
molybdenum ; aroylhydrazone ; alcohol oxidation ; catalysis ; organic solvent-free process ; TBHP in decane ; TBHP in water ; H2O2

Sažetak
Molybdenum(VI) catalysts were obtained from methanol or acetonitrile by the reaction of [MoO2(C5H7O2)2] and isonicotinoyl- or nicotinoyl- based aroylhydrazones. Reactions in methanol resulted in the formation of the mononuclear complexes [MoO2(L1–4)(MeOH)] (1a– 4a), while the ones in acetonitrile provided polynuclear complexes [MoO2(L1–4)]n (1–4). Crystals of polynuclear compound, [MoO2(L3)]n∙H2O (3∙H2O), suitable for X-ray diffraction analysis were obtained by the solvothermal procedure at 110 °C. Complexes were characterized by infrared spectroscopy (IR-ATR), nuclear magnetic resonance (NMR), elemental analysis (EA), and thermogravimetric analysis (TGA). The prepared catalysts were tested in alcohol oxidation reactions. Carveol, cyclohexanol, and butan-2-ol were investigated substrates. Because the alcohol oxidations are very challenging due to various possible pathways, the idea was to test different oxidants, H2O2, TBHP in water and decane, to optimize the researched catalytic system.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
EK-EFRR-KK.01.1.1.02.0016 - Centar izvrsnosti u kemiji - CIuK (CIuK) (Požar, Josip; Rubčić, Mirta; Biljan, Ivana, EK - KK.01.1.1.02) ( POIROT)
HRZZ-IP-2016-06-4221 - Metalosupramolekulske strukture i anorgansko-organski polioksometalatni hibridi (MOLART) (Vrdoljak, Višnja, HRZZ - 2016-06) ( POIROT)

Ustanove:
Prirodoslovno-matematički fakultet, Zagreb

Profili:

Avatar Url Višnja Vrdoljak (autor)

Avatar Url Jana Pisk (autor)

Avatar Url Mirna Mandarić (autor)

Citiraj ovu publikaciju

Mihalinec, Josipa; Pajski, Matea; Guillo, Pascal; Mandarić, Mirna; Bebić, Nikol; Pisk, Jana; Vrdoljak, Višnja
Alcohol Oxidation Assisted by Molybdenum Hydrazonato Catalysts Employing Hydroperoxide Oxidants // Catalysts, 11 (2021), 8; 881, 14 doi:10.3390/catal11080881 (međunarodna recenzija, članak, znanstveni)
Mihalinec, J., Pajski, M., Guillo, P., Mandarić, M., Bebić, N., Pisk, J. & Vrdoljak, V. (2021) Alcohol Oxidation Assisted by Molybdenum Hydrazonato Catalysts Employing Hydroperoxide Oxidants. Catalysts, 11 (8), 881, 14 doi:10.3390/catal11080881.
@article{article, year = {2021}, pages = {14}, DOI = {10.3390/catal11080881}, chapter = {881}, keywords = {molybdenum, aroylhydrazone, alcohol oxidation, catalysis, organic solvent-free process, TBHP in decane, TBHP in water, H2O2}, journal = {Catalysts}, doi = {10.3390/catal11080881}, volume = {11}, number = {8}, issn = {2073-4344}, title = {Alcohol Oxidation Assisted by Molybdenum Hydrazonato Catalysts Employing Hydroperoxide Oxidants}, keyword = {molybdenum, aroylhydrazone, alcohol oxidation, catalysis, organic solvent-free process, TBHP in decane, TBHP in water, H2O2}, chapternumber = {881} }
@article{article, year = {2021}, pages = {14}, DOI = {10.3390/catal11080881}, chapter = {881}, keywords = {molybdenum, aroylhydrazone, alcohol oxidation, catalysis, organic solvent-free process, TBHP in decane, TBHP in water, H2O2}, journal = {Catalysts}, doi = {10.3390/catal11080881}, volume = {11}, number = {8}, issn = {2073-4344}, title = {Alcohol Oxidation Assisted by Molybdenum Hydrazonato Catalysts Employing Hydroperoxide Oxidants}, keyword = {molybdenum, aroylhydrazone, alcohol oxidation, catalysis, organic solvent-free process, TBHP in decane, TBHP in water, H2O2}, chapternumber = {881} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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