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Pregled bibliografske jedinice broj: 1136318

Inorganic stereochemistry: Geometric isomerism in bis-tridentate ligand complexes


Pantalon Juraj, Natalija; Kirin, Srećko I.
Inorganic stereochemistry: Geometric isomerism in bis-tridentate ligand complexes // Coordination chemistry reviews, 445 (2021), 214051, 21 doi:10.1016/j.ccr.2021.214051 (međunarodna recenzija, pregledni rad, znanstveni)


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Naslov
Inorganic stereochemistry: Geometric isomerism in bis-tridentate ligand complexes

Autori
Pantalon Juraj, Natalija ; Kirin, Srećko I.

Izvornik
Coordination chemistry reviews (0010-8545) 445 (2021); 214051, 21

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, pregledni rad, znanstveni

Ključne riječi
stereochemistry ; isomer ; tridentate ligand ; hexacoordinated complex ; CSD survey

Sažetak
In this review, we analyze the stereochemistry of hexacoordinated metal complexes with flexible tridentate ligands. Unlike rigid ligands, which can adopt only specific coordination modes, flexible ligands open more possibilities to fine-tuning the system for a specific application. Bis-tridentate [M(A-B- A)2] complexes of flexible ligands can form three geometric isomers: mer, trans-fac, and cis-fac. The analysis of crystallographic data for 844 structures found in the Cambridge Structural Database (CSD) elucidates influences on the formation of different isomers, such as steric and electronic properties of the ligand and metal ion, type and substitution of donor atoms, and the possibility of non-covalent interactions.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
EK-EFRR-KK.01.1.1.04.0013 - Inovativna rješenja u katalitičkim proizvodnim procesima za potrebe farmaceutske industrije (CAT PHARMA) (Kirin, Srećko, EK - KK.01.1.1.04) ( POIROT)
IP-2014-09-1461 - Minimalni umjetni enzimi: Proširenje primjene posredne indukcije na nove supstrate i nove asimetrične reakcije (MArtEn) (Kirin, Srećko, HRZZ - 2014-09) ( POIROT)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Natalija Pantalon Juraj (autor)

Avatar Url Srećko Kirin (autor)

Poveznice na cjeloviti tekst rada:

doi www.sciencedirect.com doi.org

Citiraj ovu publikaciju:

Pantalon Juraj, Natalija; Kirin, Srećko I.
Inorganic stereochemistry: Geometric isomerism in bis-tridentate ligand complexes // Coordination chemistry reviews, 445 (2021), 214051, 21 doi:10.1016/j.ccr.2021.214051 (međunarodna recenzija, pregledni rad, znanstveni)
Pantalon Juraj, N. & Kirin, S. (2021) Inorganic stereochemistry: Geometric isomerism in bis-tridentate ligand complexes. Coordination chemistry reviews, 445, 214051, 21 doi:10.1016/j.ccr.2021.214051.
@article{article, year = {2021}, pages = {21}, DOI = {10.1016/j.ccr.2021.214051}, chapter = {214051}, keywords = {stereochemistry, isomer, tridentate ligand, hexacoordinated complex, CSD survey}, journal = {Coordination chemistry reviews}, doi = {10.1016/j.ccr.2021.214051}, volume = {445}, issn = {0010-8545}, title = {Inorganic stereochemistry: Geometric isomerism in bis-tridentate ligand complexes}, keyword = {stereochemistry, isomer, tridentate ligand, hexacoordinated complex, CSD survey}, chapternumber = {214051} }
@article{article, year = {2021}, pages = {21}, DOI = {10.1016/j.ccr.2021.214051}, chapter = {214051}, keywords = {stereochemistry, isomer, tridentate ligand, hexacoordinated complex, CSD survey}, journal = {Coordination chemistry reviews}, doi = {10.1016/j.ccr.2021.214051}, volume = {445}, issn = {0010-8545}, title = {Inorganic stereochemistry: Geometric isomerism in bis-tridentate ligand complexes}, keyword = {stereochemistry, isomer, tridentate ligand, hexacoordinated complex, CSD survey}, chapternumber = {214051} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


Citati:





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