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Pregled bibliografske jedinice broj: 1132520

Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands


Matijaković Mlinarić, Nives; Penić, Nikolina; Kukovec, Boris-Marko; Đaković, Marijana
Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands // Crystals, 11 (2021), 6; 697, 11 doi:10.3390/cryst11060697 (međunarodna recenzija, članak, znanstveni)


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Naslov
Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands

Autori
Matijaković Mlinarić, Nives ; Penić, Nikolina ; Kukovec, Boris-Marko ; Đaković, Marijana

Izvornik
Crystals (2073-4352) 11 (2021), 6; 697, 11

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
coordination networks ; cadmium(II) ; thiocyanate ; 3-acetamidopyridine ; nicotinic acid hydrazide ; chalcogen bonds ; hydrogen-bond motifs

Sažetak
Two cadmium(II) coordination polymers, with thiocyanate and pyridine-based ligands e.g., 3- acetamidopyridine (3-Acpy) and niazid (nicotinic acid hydrazide, nia), namely one- dimensional {; ; ; [Cd(SCN)2(3-Acpy)]}; ; ; n (1) and two- dimensional {; ; ; [Cd(SCN)2(nia)]}; ; ; n (2), are prepared in the mixture of water and ethanol. The adjacent cadmium(II) ions in 1 are bridged by two N, S-thiocyanate ions and an N, O-bridging 3-Acpy molecule, forming infinite one- dimensional polymeric chains, which are assembled by the intermolecular N–H∙∙∙S hydrogen bonds in one direction and by the intermolecular S∙∙∙S chalcogen bonds in another direction. Within the coordination network of 2, the adjacent cadmium(II) ions are bridged by N, S-thiocyanate ions in one direction and by N, O, N’-chelating and bridging nia molecules in another direction. The coordination networks of 2 are assembled by the intermolecular N–H∙∙∙S and N–H∙∙∙N hydrogen bonds and S∙∙∙S chalcogen bonds. Being the only supramolecular interactions responsible for assembling the polymer chains of 1 in the particular direction, the chalcogen S∙∙∙S bonds are more significant in the structure of 1, whilst the chalcogen S∙∙∙S bonds which act in cooperation with the N–H∙∙∙S and N–H∙∙∙N hydrogen bonds are of less significance in the structure of 2.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
HRZZ-IP-2019-04-1242 - Od oblika do funkcije: Fleksibilni kristalni materijali s kontroliranim mehaničkim odzivom (FlexibleCrystals) (Đaković, Marijana, HRZZ - 2019-04) ( POIROT)

Ustanove:
Kemijsko-tehnološki fakultet, Split,
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb

Citiraj ovu publikaciju

Matijaković Mlinarić, Nives; Penić, Nikolina; Kukovec, Boris-Marko; Đaković, Marijana
Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands // Crystals, 11 (2021), 6; 697, 11 doi:10.3390/cryst11060697 (međunarodna recenzija, članak, znanstveni)
Matijaković Mlinarić, N., Penić, N., Kukovec, B. & Đaković, M. (2021) Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands. Crystals, 11 (6), 697, 11 doi:10.3390/cryst11060697.
@article{article, year = {2021}, pages = {11}, DOI = {10.3390/cryst11060697}, chapter = {697}, keywords = {coordination networks, cadmium(II), thiocyanate, 3-acetamidopyridine, nicotinic acid hydrazide, chalcogen bonds, hydrogen-bond motifs}, journal = {Crystals}, doi = {10.3390/cryst11060697}, volume = {11}, number = {6}, issn = {2073-4352}, title = {Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands}, keyword = {coordination networks, cadmium(II), thiocyanate, 3-acetamidopyridine, nicotinic acid hydrazide, chalcogen bonds, hydrogen-bond motifs}, chapternumber = {697} }
@article{article, year = {2021}, pages = {11}, DOI = {10.3390/cryst11060697}, chapter = {697}, keywords = {coordination networks, cadmium(II), thiocyanate, 3-acetamidopyridine, nicotinic acid hydrazide, chalcogen bonds, hydrogen-bond motifs}, journal = {Crystals}, doi = {10.3390/cryst11060697}, volume = {11}, number = {6}, issn = {2073-4352}, title = {Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands}, keyword = {coordination networks, cadmium(II), thiocyanate, 3-acetamidopyridine, nicotinic acid hydrazide, chalcogen bonds, hydrogen-bond motifs}, chapternumber = {697} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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