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Pregled bibliografske jedinice broj: 1132119

Potentiometric Surfactant Sensor Based on 1,3- Dihexadecyl-1H-benzo[d]imidazol-3-ium for Anionic Surfactants in Detergents and Household Care Products


Sakač, Nikola; Madunić-Čačić, Dubravka; Marković, Dean; Hok, Lucija; Vianello, Robert; Šarkanj, Bojan; Đurin, Bojan; Hajdek, Krunoslav; Smoljan, Božo; Milardović, Stjepan et al.
Potentiometric Surfactant Sensor Based on 1,3- Dihexadecyl-1H-benzo[d]imidazol-3-ium for Anionic Surfactants in Detergents and Household Care Products // Molecules, 26 (2021), 12; 3627, 14 doi:10.3390/molecules26123627 (međunarodna recenzija, članak, znanstveni)


CROSBI ID: 1132119 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Potentiometric Surfactant Sensor Based on 1,3- Dihexadecyl-1H-benzo[d]imidazol-3-ium for Anionic Surfactants in Detergents and Household Care Products

Autori
Sakač, Nikola ; Madunić-Čačić, Dubravka ; Marković, Dean ; Hok, Lucija ; Vianello, Robert ; Šarkanj, Bojan ; Đurin, Bojan ; Hajdek, Krunoslav ; Smoljan, Božo ; Milardović, Stjepan ; Matasović, Brunislav ; Jozanović, Marija

Izvornik
Molecules (1420-3049) 26 (2021), 12; 3627, 14

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
anionic surfactants ; sensor ; potentiometry ; detergents ; nonionic surfactants ; household detergents ; molecular dynamics simulations

Sažetak
A 1, 3-dihexadecyl-1H-benzo[d]imidazol-3-ium- tetraphenylborate (DHBI-TPB) ion-pair implemented in DHBI-TPB surfactant sensor was used for the potentiometric quantification of anionic surfactants in detergents and commercial household care products. The DHBI-TPB ion-pair was characterized by FTIR spectroscopy and computational analysis which revealed a crucial contribution of the C–H∙∙∙π contacts for the optimal complex formation. The DHBI-TPB sensor potentiometric response showed excellent analytical properties and Nernstian slope for SDS (60.1 mV/decade) with LOD 3.2 × 10−7 M ; and DBS (58.4 mV/decade) with LOD 6.1 × 10−7 M was obtained. The sensor possesses exceptional resistance to different organic and inorganic interferences in broad pH (2–10) range. DMIC used as a titrant demonstrated superior analytical performances for potentiometric titrations of SDS, compared to other tested cationic surfactants (DMIC > CTAB > CPC > Hyamine 1622). The combination of DHBI-TPB sensor and DMIC was successfully employed to perform titrations of the highly soluble alkane sulfonate homologues. Nonionic surfactants (increased concentration and number of EO groups) had a negative impact on anionic surfactant titration curves and a signal change. The DHBI-TPB sensor was effectively employed for the determination of technical grade anionic surfactants presenting the recoveries from 99.5 to 101.3%. The sensor was applied on twelve powered samples as well as liquid-gel and handwashing home care detergents containing anionic surfactants. The obtained results showed good agreement compared to the outcomes measured by ISE surfactant sensor and a two-phase titration method. The developed DHBI-TPB surfactant sensor could be used for quality control in industry and has great potential in environmental monitoring.

Izvorni jezik
Engleski

Znanstvena područja
Kemija, Kemijsko inženjerstvo, Interdisciplinarne tehničke znanosti



POVEZANOST RADA


Projekti:
IP-2019-04-8846 - In-silico potpomognut dizajn supstrata za hvatanje CO2 u katalitičkoj formaciji karbonata i karbamata (INDICATIOR) (Marković, Dean, HRZZ - 2019-04) ( POIROT)
HRZZ-IP-2020-02-8090 - Dizajn, sinteza i računalna analiza novih optičkih kemijskih pH osjetilnih derivata benzazola (BenzpHSens) (Vianello, Robert, HRZZ - 2020-02) ( POIROT)

Ustanove:
Institut "Ruđer Bošković", Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb,
Geotehnički fakultet, Varaždin,
Sveučilište u Osijeku - Odjel za kemiju,
Sveučilište u Rijeci - Odjel za biotehnologiju,
Sveučilište Sjever, Koprivnica

Poveznice na cjeloviti tekst rada:

doi www.mdpi.com doi.org fulir.irb.hr

Citiraj ovu publikaciju:

Sakač, Nikola; Madunić-Čačić, Dubravka; Marković, Dean; Hok, Lucija; Vianello, Robert; Šarkanj, Bojan; Đurin, Bojan; Hajdek, Krunoslav; Smoljan, Božo; Milardović, Stjepan et al.
Potentiometric Surfactant Sensor Based on 1,3- Dihexadecyl-1H-benzo[d]imidazol-3-ium for Anionic Surfactants in Detergents and Household Care Products // Molecules, 26 (2021), 12; 3627, 14 doi:10.3390/molecules26123627 (međunarodna recenzija, članak, znanstveni)
Sakač, N., Madunić-Čačić, D., Marković, D., Hok, L., Vianello, R., Šarkanj, B., Đurin, B., Hajdek, K., Smoljan, B. & Milardović, S. (2021) Potentiometric Surfactant Sensor Based on 1,3- Dihexadecyl-1H-benzo[d]imidazol-3-ium for Anionic Surfactants in Detergents and Household Care Products. Molecules, 26 (12), 3627, 14 doi:10.3390/molecules26123627.
@article{article, author = {Saka\v{c}, Nikola and Maduni\'{c}-\v{C}a\v{c}i\'{c}, Dubravka and Markovi\'{c}, Dean and Hok, Lucija and Vianello, Robert and \v{S}arkanj, Bojan and \DJurin, Bojan and Hajdek, Krunoslav and Smoljan, Bo\v{z}o and Milardovi\'{c}, Stjepan and Matasovi\'{c}, Brunislav and Jozanovi\'{c}, Marija}, year = {2021}, pages = {14}, DOI = {10.3390/molecules26123627}, chapter = {3627}, keywords = {anionic surfactants, sensor, potentiometry, detergents, nonionic surfactants, household detergents, molecular dynamics simulations}, journal = {Molecules}, doi = {10.3390/molecules26123627}, volume = {26}, number = {12}, issn = {1420-3049}, title = {Potentiometric Surfactant Sensor Based on 1,3- Dihexadecyl-1H-benzo[d]imidazol-3-ium for Anionic Surfactants in Detergents and Household Care Products}, keyword = {anionic surfactants, sensor, potentiometry, detergents, nonionic surfactants, household detergents, molecular dynamics simulations}, chapternumber = {3627} }
@article{article, author = {Saka\v{c}, Nikola and Maduni\'{c}-\v{C}a\v{c}i\'{c}, Dubravka and Markovi\'{c}, Dean and Hok, Lucija and Vianello, Robert and \v{S}arkanj, Bojan and \DJurin, Bojan and Hajdek, Krunoslav and Smoljan, Bo\v{z}o and Milardovi\'{c}, Stjepan and Matasovi\'{c}, Brunislav and Jozanovi\'{c}, Marija}, year = {2021}, pages = {14}, DOI = {10.3390/molecules26123627}, chapter = {3627}, keywords = {anionic surfactants, sensor, potentiometry, detergents, nonionic surfactants, household detergents, molecular dynamics simulations}, journal = {Molecules}, doi = {10.3390/molecules26123627}, volume = {26}, number = {12}, issn = {1420-3049}, title = {Potentiometric Surfactant Sensor Based on 1,3- Dihexadecyl-1H-benzo[d]imidazol-3-ium for Anionic Surfactants in Detergents and Household Care Products}, keyword = {anionic surfactants, sensor, potentiometry, detergents, nonionic surfactants, household detergents, molecular dynamics simulations}, chapternumber = {3627} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus
  • MEDLINE


Citati:





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