Schiff bases as halogen bond donors in crystal engineering of cocrystals (CROSBI ID 704067)
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Podaci o odgovornosti
Baus Topić, Nea ; Cinčić, Dominik
engleski
Schiff bases as halogen bond donors in crystal engineering of cocrystals
In the past two decades, halogen bonding has been shown as an effective and predictable tool in crystal engineering [1]. It has been predominantly investigated in multicomponent crystals consisting of organic perhalogenated compounds as halogen bond donors and various organic and metal-organic compounds as halogen bond acceptors [2]. While many multicomponent systems contain Schiff bases as halogen bond acceptors [3], there are scarce examples of those that contain them as halogen bond donors [4]. In this work, we have prepared two peripherally perhalogenated Schiff bases by reaction of 2, 3, 5, 6-tetrafluoro-4-iodoaniline with salicylaldehyde (itfasal) or ortho- vanillin (itfaovan). Both Schiff bases were cocrystallized in 2:1 molar ratio with selected acceptors: 4, 4’- bipyridine (bpy), 1, 4- diazabicyclo[2.2.2]octane (dabco) and 1, 2- bis(4-pyridyl)ethane (bpean). Cocrystals were prepared by liquid-assisted grinding and crystallization from ethanol and characterized by X-ray diffraction methods. Structural characterization revealed that in all six cocrystals itfasal and itfaovan are bonded with acceptors via I∙∙∙N halogen bonds. [1] G. Cavallo, P. Metrangolo, R. Milani, T. Pilati, A. Priimagi, G. Resnati, G. Terraneo, Chem. Rev. 116 (2016) 2478. [2] C. R. Groom, I. J. Bruno, M. P. Lightfoot, S. C. Ward, Acta Cryst. B 72 (2016), 171. [3] A. Carletta, M. Zbačnik, M. Vitković, N. Tumanov, V. Stilinović, J. Wouters, D. Cinčić, CrystEngComm 36 (2018), 5332. [4] Y. Wang, H. Shang, B. Li, H. Zhang, S. Jiang, CrystEngComm 19 (2017) 3801.
Schiff base ; halogen bond ; cocrystal
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Podaci o prilogu
83-83.
2021.
objavljeno
Podaci o matičnoj publikaciji
Solid State Science and Research 2021, Online Meeting : Book of Abstracts
Biliškov, Nikola ; Brekalo, Ivana ; Martinez, Valentina
Zagreb: Institut Ruđer Bošković
978-953-7941-35-2
Podaci o skupu
Solid-State Science & Research 2021 (SCIRES2021)
poster
10.07.2021-11.07.2021
Zagreb, Hrvatska