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Pregled bibliografske jedinice broj: 1129008

Elucidating the Origins of a Range of Diverse Flexible Responses in Crystalline Coordination Polymers


Pisačić, Mateja; Biljan, Ivana; Kodrin, Ivan; Popov, Nina; Soldin, Željka; Đaković, Marijana
Elucidating the Origins of a Range of Diverse Flexible Responses in Crystalline Coordination Polymers // Chemistry of materials, 33 (2021), 10; 3660-3668 doi:10.1021/acs.chemmater.1c00539 (međunarodna recenzija, članak, znanstveni)


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Naslov
Elucidating the Origins of a Range of Diverse Flexible Responses in Crystalline Coordination Polymers

Autori
Pisačić, Mateja ; Biljan, Ivana ; Kodrin, Ivan ; Popov, Nina ; Soldin, Željka ; Đaković, Marijana

Izvornik
Chemistry of materials (0897-4756) 33 (2021), 10; 3660-3668

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Crystals ; Plastic ; Deformation ; Flexibility ; Molecular interactions

Sažetak
The mechanical adaptability of a family of six one-dimensional crystalline coordination polymers (CPs) of cadmium ([CdX2(3-X′py)2]n ; 1: X = Br, X′ = Cl, 2: X = I, X′ = Cl, 3: X = I, X′ = Br, 4: X = Cl, X′ = I, 5: X = Br, X′ = I, and 6: X, X′ = I) to applied external force was examined, and a plethora of flexible responses was noticed. While two of the six CPs (4 and 6) were slightly elastic, the remaining four CPs (1–3 and 5) presented variable plastic deformation ; three of these (1–3) displayed exceptional crystal flow, and one (2) demonstrated unprecedented ductility of crystalline metal–organic material. The feature was examined by theory and custom-designed experiments, and it was shown that specific and directional intermolecular interactions are not only the most influential structural feature in determining the type of mechanical responses (i.e., elastic vs plastic), with interlocking of adjacent molecules playing only a supportive role, but also an unavoidable tool for dialing-in a diversity of plastic responses in Cd(II) coordination polymers.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
HRZZ-IP-2019-04-1242 - Od oblika do funkcije: Fleksibilni kristalni materijali s kontroliranim mehaničkim odzivom (FlexibleCrystals) (Đaković, Marijana, HRZZ - 2019-04) ( POIROT)

Ustanove:
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb

Profili:

Avatar Url Marijana Đaković (autor)

Avatar Url Željka Soldin (autor)

Avatar Url Ivana Biljan (autor)

Avatar Url Mateja Pisačić (autor)

Avatar Url Nina Popov (autor)

Avatar Url Ivan Kodrin (autor)

Citiraj ovu publikaciju

Pisačić, Mateja; Biljan, Ivana; Kodrin, Ivan; Popov, Nina; Soldin, Željka; Đaković, Marijana
Elucidating the Origins of a Range of Diverse Flexible Responses in Crystalline Coordination Polymers // Chemistry of materials, 33 (2021), 10; 3660-3668 doi:10.1021/acs.chemmater.1c00539 (međunarodna recenzija, članak, znanstveni)
Pisačić, M., Biljan, I., Kodrin, I., Popov, N., Soldin, Ž. & Đaković, M. (2021) Elucidating the Origins of a Range of Diverse Flexible Responses in Crystalline Coordination Polymers. Chemistry of materials, 33 (10), 3660-3668 doi:10.1021/acs.chemmater.1c00539.
@article{article, year = {2021}, pages = {3660-3668}, DOI = {10.1021/acs.chemmater.1c00539}, keywords = {Crystals, Plastic, Deformation, Flexibility, Molecular interactions}, journal = {Chemistry of materials}, doi = {10.1021/acs.chemmater.1c00539}, volume = {33}, number = {10}, issn = {0897-4756}, title = {Elucidating the Origins of a Range of Diverse Flexible Responses in Crystalline Coordination Polymers}, keyword = {Crystals, Plastic, Deformation, Flexibility, Molecular interactions} }
@article{article, year = {2021}, pages = {3660-3668}, DOI = {10.1021/acs.chemmater.1c00539}, keywords = {Crystals, Plastic, Deformation, Flexibility, Molecular interactions}, journal = {Chemistry of materials}, doi = {10.1021/acs.chemmater.1c00539}, volume = {33}, number = {10}, issn = {0897-4756}, title = {Elucidating the Origins of a Range of Diverse Flexible Responses in Crystalline Coordination Polymers}, keyword = {Crystals, Plastic, Deformation, Flexibility, Molecular interactions} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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