Use of a “Shoe-Last” Solid-State Template in the Mechanochemical Synthesis of High-Porosity RHO-Zinc Imidazolate (CROSBI ID 294100)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Brekalo, Ivana ; Kane, Christopher M. ; Ley, Amanda N. ; Ramirez, Joseph R. ; Friščić, Tomislav ; Holman, K. Travis
engleski
Use of a “Shoe-Last” Solid-State Template in the Mechanochemical Synthesis of High-Porosity RHO-Zinc Imidazolate
We report the first use of a nonionic solid (NIS) as a template in mechanosynthesis of a metal–organic framework. Through eight intermolecular C–H···O hydrogen bonds, the macrocyclic MeMeCH2 template predictably functions as a “shoe-last” for the assembly of double-eight rings in the liquid-assisted reaction of ZnO and imidazole (ImH). The resulting new form of ZnIm2 (namely xMeMeCH2@RHO-Zn16Im32) is available in multigram amounts, highly porous, and thermally stable.
zeolitic imidazolate frameworks ; mechanochemistry ; templation ; porous materials
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Podaci o izdanju
140 (32)
2018.
10104-10108
objavljeno
0002-7863
10.1021/jacs.8b05471
Povezanost rada
Kemija