Distribution of three ions in the thin film experiment (CROSBI ID 489373)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa
Podaci o odgovornosti
Lovrić, Milivoj ; Komorsky-Lovrić, Šebojka
engleski
Distribution of three ions in the thin film experiment
In the theoretical model it is assumed that a graphite disk electrode is covered by a thin film of the solution of decamethylferrocene and some supporting electrolyte in nitrobenzene and immersed in an aqueous solution of the same electrolyte. Oxidation of decamethylferrocene is accompanied by the transfer of anions of the electrolyte from water into nitrobenzene. The flux of decamethylferrocenium cations at the electrode surface and the flux of anions at the liquid / liquid interface are separated by the thickness of the film, but the electroneutrality is ensured by the migration of ionic species through the film. Theoretical concentration profiles of ionic species in the film are reported for cyclic voltammetry.
liquid / liquid interface; ionic transfer; migration; diffusion; cyclic voltammetry; decamethylferrocene
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Podaci o prilogu
36-36-x.
2003.
objavljeno
Podaci o matičnoj publikaciji
Book of abstracts / 36th Heyrovsky Discussion ; Electrochemistry of Biological Systems and their Models
Heyrovsky, M.
Prag: Jaroslav Heyrovsky Institute
Podaci o skupu
36 th Heyrovsky Discussion ; Electrochemistry of Biological Systems and their Models
poster
15.06.2003-19.06.2003
Třešť, Češka Republika