Pretražite po imenu i prezimenu autora, mentora, urednika, prevoditelja

Napredna pretraga

Pregled bibliografske jedinice broj: 111448

Lithiation/Silylation of Ethyl 2-Alkyl-1-Trimethylsilylcycloprop-2-ene-1-Carboxylate. Experimental and Computational Study


Zrinski, Irena; Gadanji, Gordana; Eckert-Maksić, Mirjana
Lithiation/Silylation of Ethyl 2-Alkyl-1-Trimethylsilylcycloprop-2-ene-1-Carboxylate. Experimental and Computational Study // New Journal of Chemistry, 27 (2003), 8; 1270-1276 (međunarodna recenzija, članak, znanstveni)


Naslov
Lithiation/Silylation of Ethyl 2-Alkyl-1-Trimethylsilylcycloprop-2-ene-1-Carboxylate. Experimental and Computational Study

Autori
Zrinski, Irena ; Gadanji, Gordana ; Eckert-Maksić, Mirjana

Izvornik
New Journal of Chemistry (1144-0546) 27 (2003), 8; 1270-1276

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
trimethylsilyl-substituted allene; lithiation of cyclopropene; ring opening; silyl ketene acetal; DFT calculations

Sažetak
The formation of novel trimethylsilyl-substituted allenes, including silyl ketene acetals incorporating an allenic moiety, by lithiation/silylation of ethyl 2-alkyl-1-trimethylsilylcycloprop-2-ene-1-carboxylate, is described. The reaction involves formation of silyl ketene acetal 3 (3a) which upon aqueous work-up gives diasteromeric allenes 4' (4'a) and 4'' (4''a). Becke3LYP/6-311+G** calculations were also carried out to provide geometries, energies and insights into the electronic structure of the proposed reaction intermediates.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
0098056

Ustanove
Institut "Ruđer Bošković", Zagreb

Citiraj ovu publikaciju

Zrinski, Irena; Gadanji, Gordana; Eckert-Maksić, Mirjana
Lithiation/Silylation of Ethyl 2-Alkyl-1-Trimethylsilylcycloprop-2-ene-1-Carboxylate. Experimental and Computational Study // New Journal of Chemistry, 27 (2003), 8; 1270-1276 (međunarodna recenzija, članak, znanstveni)
Zrinski, I., Gadanji, G. & Eckert-Maksić, M. (2003) Lithiation/Silylation of Ethyl 2-Alkyl-1-Trimethylsilylcycloprop-2-ene-1-Carboxylate. Experimental and Computational Study. New Journal of Chemistry, 27 (8), 1270-1276.
@article{article, year = {2003}, pages = {1270-1276}, keywords = {trimethylsilyl-substituted allene, lithiation of cyclopropene, ring opening, silyl ketene acetal, DFT calculations}, journal = {New Journal of Chemistry}, volume = {27}, number = {8}, issn = {1144-0546}, title = {Lithiation/Silylation of Ethyl 2-Alkyl-1-Trimethylsilylcycloprop-2-ene-1-Carboxylate. Experimental and Computational Study}, keyword = {trimethylsilyl-substituted allene, lithiation of cyclopropene, ring opening, silyl ketene acetal, DFT calculations} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


Uključenost u ostale bibliografske baze podataka:


  • Chemical Abstracts