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Pregled bibliografske jedinice broj: 1103238

Synthesis of Ti(OH)OF ⋅ 0.66 H 2 O in Imidazolium‐based Ionic Liquids


Sieland, Melanie; Camus‐Genot, Valentine; Djerdj, Igor; Smarsly, Bernd M.
Synthesis of Ti(OH)OF ⋅ 0.66 H 2 O in Imidazolium‐based Ionic Liquids // ChemistryOpen, 10 (2021), 2; 181-188 doi:10.1002/open.202000256 (međunarodna recenzija, članak, znanstveni)


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Naslov
Synthesis of Ti(OH)OF ⋅ 0.66 H 2 O in Imidazolium‐based Ionic Liquids

Autori
Sieland, Melanie ; Camus‐Genot, Valentine ; Djerdj, Igor ; Smarsly, Bernd M.

Izvornik
ChemistryOpen (2191-1363) 10 (2021), 2; 181-188

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
ionic ; liquid ; imidazolium-based ; titanium

Sažetak
The influence of the cation of imidazolium‐ derived ionic liquids (ILs) on a low‐ temperature solution‐based synthesis of hexagonal tungsten bronze (HTB) type Ti(OH)OF ⋅ 0.66 H2O and bronze‐type TiO2(B) is investigated. The IL (Cxmim BF4) acts as solvent and also as reaction partner with respect to the decomposition of [BF4]−, releasing F−. In the present study, the chain length of the alkyl chain side groups attached to the imidazolium ring was varied (C2mim BF4 to C10mim BF4), and the obtained solids were analyzed by Powder X‐Ray diffraction (PXRD) followed by Rietveld refinement. As a main finding these analyses indicate a transformation of Ti(OH)OF ⋅ 0.66 H2O into TiO2(B), and upon prolonged reaction time finally also into anatase TiO2. Rietveld analysis suggests that when using ILs with longer alkyl chains, the conversion of Ti(OH)OF ⋅ 0.66 H2O is slower compared to syntheses performed with smaller alkyl chains. Hence, Ti(OH)OF ⋅ 0.66 H2O appears to be metastable and is stabilized by long‐chain ILs serving as surfactant attached to the crystallites’ surface. In this view, the ILs shield the nanoparticles and thus slow down the conversion into the more stable compounds. This confirms previous findings that ILs act as both, solvent and reaction medium in this reaction, thus enabling the synthesis of peculiar Ti‐oxides.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Ustanove:
Sveučilište u Osijeku - Odjel za kemiju

Profili:

Avatar Url Igor Đerđ (autor)

Citiraj ovu publikaciju

Sieland, Melanie; Camus‐Genot, Valentine; Djerdj, Igor; Smarsly, Bernd M.
Synthesis of Ti(OH)OF ⋅ 0.66 H 2 O in Imidazolium‐based Ionic Liquids // ChemistryOpen, 10 (2021), 2; 181-188 doi:10.1002/open.202000256 (međunarodna recenzija, članak, znanstveni)
Sieland, M., Camus‐Genot, V., Djerdj, I. & Smarsly, B. (2021) Synthesis of Ti(OH)OF ⋅ 0.66 H 2 O in Imidazolium‐based Ionic Liquids. ChemistryOpen, 10 (2), 181-188 doi:10.1002/open.202000256.
@article{article, year = {2021}, pages = {181-188}, DOI = {10.1002/open.202000256}, keywords = {ionic, liquid, imidazolium-based, titanium}, journal = {ChemistryOpen}, doi = {10.1002/open.202000256}, volume = {10}, number = {2}, issn = {2191-1363}, title = {Synthesis of Ti(OH)OF ⋅ 0.66 H 2 O in Imidazolium‐based Ionic Liquids}, keyword = {ionic, liquid, imidazolium-based, titanium} }
@article{article, year = {2021}, pages = {181-188}, DOI = {10.1002/open.202000256}, keywords = {ionic, liquid, imidazolium-based, titanium}, journal = {ChemistryOpen}, doi = {10.1002/open.202000256}, volume = {10}, number = {2}, issn = {2191-1363}, title = {Synthesis of Ti(OH)OF ⋅ 0.66 H 2 O in Imidazolium‐based Ionic Liquids}, keyword = {ionic, liquid, imidazolium-based, titanium} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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