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Pregled bibliografske jedinice broj: 1099234

In-operando diffraction and spectroscopic evaluation of pure, Zr-, and Ce-doped vanadium dioxide thermochromic films derived via glycolate synthesis


Kurajica, Stanislav; Mandić, Vilko; Panžić, Ivana; Gaboardi, Mattia; Mužina, Katarina; Lozančić, Ana; Šipušić, Juraj; Munda, Ivana Katarina; Višić, Lucija; Lučić Blagojević, Sanja et al.
In-operando diffraction and spectroscopic evaluation of pure, Zr-, and Ce-doped vanadium dioxide thermochromic films derived via glycolate synthesis // Nanomaterials, 10 (2020), 12; 2537, 20 doi:10.3390/nano10122537 (međunarodna recenzija, članak, znanstveni)


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Naslov
In-operando diffraction and spectroscopic evaluation of pure, Zr-, and Ce-doped vanadium dioxide thermochromic films derived via glycolate synthesis

Autori
Kurajica, Stanislav ; Mandić, Vilko ; Panžić, Ivana ; Gaboardi, Mattia ; Mužina, Katarina ; Lozančić, Ana ; Šipušić, Juraj ; Munda, Ivana Katarina ; Višić, Lucija ; Lučić Blagojević, Sanja ; Gigli, Lara ; Rikkert Plaisier, Jasper

Izvornik
Nanomaterials (2079-4991) 10 (2020), 12; 2537, 20

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
smart window ; vanadium dioxide ; Zr-doping ; Ce-doping ; thermochromic transition ; structural properties ; IR transmission/reflection ; in-operando ; GIXRD-Raman f(T) setup ; multi-channel characterisation

Sažetak
Pure and doped vanadia (VO2, V0.98Zr0.02O2, V0.98Ce0.02O2) samples were prepared by wet chemistry synthesis from vanadyl glycolate intermediate phase and tape casted into films. Combining in-operando grazing incidence synchrotron X-ray di raction and Raman spectroscopy, we studied the structural evolution of the films under isothermal conditions. The setup allowed assessment of the thermochromic functionality with continuous monitoring of the monoclinic to tetragonal transition in pure and doped vanadia phases, responsible for the transmission and reflection of light in the infrared part of the solar spectrum. The materials characterisation by X-ray di raction beamline (MCX) goniometer demonstrated ideal performance, combining flexible geometry, high resolution, and the potential to accommodate the multi-channel equipment for in-operando characterisation. This method proved viable for evaluating the relevant structural and physical, and thereof functional properties of these systems. We revealed that dopants reduce the transition temperature by 5°C on average. The synthetic route of the films was held responsible for the observed phase separation. The more favourable behaviour of cerium- doped sample was attributed to cerium alkoxide behaviour. In addition, structural, microstructural, thermal, and spectroscopic characterisation on powder samples was performed to gain more insight into the development of the phases that are responsible for thermochromic features in a broader range of doping ratios. The influence of the dopants on the extent of the thermochromic transition (transmission to reflection hysteresis) was also evaluated using (micro) structural, thermal and spectroscopic methods of powder samples. Characterisations showed that zirconium doping in 2, 4, and 6 mol% significantly influenced the phase composition and morphology of the precursor. Vanadium oxides other than VO2 can easily crystallise ; however, a thermal treatment regime that allowed crystallisation of VO2 as a single phase was established.

Izvorni jezik
Engleski

Znanstvena područja
Kemija, Kemijsko inženjerstvo, Temeljne tehničke znanosti

Napomena
This article belongs to the Special Issue Probing
Single Events at the Nanoscale.



POVEZANOST RADA


Projekti:
HRZZ-UIP-2019-04-2367 - Fenomeni na površini tijekom priprave naprednih nanokompozita infiltracijom i funkcionalizacijom poroznih materijala (SLIPPERYSLOPE) (Mandić, Vilko, HRZZ - 2019-04) ( POIROT)
HRZZ-IP-2018-01-2963 - Hidrotermalna sinteza dopiranog cerij oksidnog nanokatalizatora (HOuDiNI) (Kurajica, Stanislav, HRZZ - 2018-01) ( POIROT)
HRZZ-PZS-2019-02-1555 - Fotonaponska-geopolimerna fasada: uloga vode-kisika u naprednom sklapanju filmova kompozitnih materijala (PV-WALL) (Mandić, Vilko, HRZZ - 2019-02) ( POIROT)

Ustanove:
Institut "Ruđer Bošković", Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb

Poveznice na cjeloviti tekst rada:

doi www.mdpi.com fulir.irb.hr doi.org

Citiraj ovu publikaciju:

Kurajica, Stanislav; Mandić, Vilko; Panžić, Ivana; Gaboardi, Mattia; Mužina, Katarina; Lozančić, Ana; Šipušić, Juraj; Munda, Ivana Katarina; Višić, Lucija; Lučić Blagojević, Sanja et al.
In-operando diffraction and spectroscopic evaluation of pure, Zr-, and Ce-doped vanadium dioxide thermochromic films derived via glycolate synthesis // Nanomaterials, 10 (2020), 12; 2537, 20 doi:10.3390/nano10122537 (međunarodna recenzija, članak, znanstveni)
Kurajica, S., Mandić, V., Panžić, I., Gaboardi, M., Mužina, K., Lozančić, A., Šipušić, J., Munda, I., Višić, L. & Lučić Blagojević, S. (2020) In-operando diffraction and spectroscopic evaluation of pure, Zr-, and Ce-doped vanadium dioxide thermochromic films derived via glycolate synthesis. Nanomaterials, 10 (12), 2537, 20 doi:10.3390/nano10122537.
@article{article, author = {Kurajica, Stanislav and Mandi\'{c}, Vilko and Pan\v{z}i\'{c}, Ivana and Gaboardi, Mattia and Mu\v{z}ina, Katarina and Lozan\v{c}i\'{c}, Ana and \v{S}ipu\v{s}i\'{c}, Juraj and Munda, Ivana Katarina and Vi\v{s}i\'{c}, Lucija and Lu\v{c}i\'{c} Blagojevi\'{c}, Sanja and Gigli, Lara and Rikkert Plaisier, Jasper}, year = {2020}, pages = {20}, DOI = {10.3390/nano10122537}, chapter = {2537}, keywords = {smart window, vanadium dioxide, Zr-doping, Ce-doping, thermochromic transition, structural properties, IR transmission/reflection, in-operando, GIXRD-Raman f(T) setup, multi-channel characterisation}, journal = {Nanomaterials}, doi = {10.3390/nano10122537}, volume = {10}, number = {12}, issn = {2079-4991}, title = {In-operando diffraction and spectroscopic evaluation of pure, Zr-, and Ce-doped vanadium dioxide thermochromic films derived via glycolate synthesis}, keyword = {smart window, vanadium dioxide, Zr-doping, Ce-doping, thermochromic transition, structural properties, IR transmission/reflection, in-operando, GIXRD-Raman f(T) setup, multi-channel characterisation}, chapternumber = {2537} }
@article{article, author = {Kurajica, Stanislav and Mandi\'{c}, Vilko and Pan\v{z}i\'{c}, Ivana and Gaboardi, Mattia and Mu\v{z}ina, Katarina and Lozan\v{c}i\'{c}, Ana and \v{S}ipu\v{s}i\'{c}, Juraj and Munda, Ivana Katarina and Vi\v{s}i\'{c}, Lucija and Lu\v{c}i\'{c} Blagojevi\'{c}, Sanja and Gigli, Lara and Rikkert Plaisier, Jasper}, year = {2020}, pages = {20}, DOI = {10.3390/nano10122537}, chapter = {2537}, keywords = {smart window, vanadium dioxide, Zr-doping, Ce-doping, thermochromic transition, structural properties, IR transmission/reflection, in-operando, GIXRD-Raman f(T) setup, multi-channel characterisation}, journal = {Nanomaterials}, doi = {10.3390/nano10122537}, volume = {10}, number = {12}, issn = {2079-4991}, title = {In-operando diffraction and spectroscopic evaluation of pure, Zr-, and Ce-doped vanadium dioxide thermochromic films derived via glycolate synthesis}, keyword = {smart window, vanadium dioxide, Zr-doping, Ce-doping, thermochromic transition, structural properties, IR transmission/reflection, in-operando, GIXRD-Raman f(T) setup, multi-channel characterisation}, chapternumber = {2537} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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