Pregled bibliografske jedinice broj: 109793
Electrochemical study of the chromium electrode behaviour in borate buffer solution
Electrochemical study of the chromium electrode behaviour in borate buffer solution // Journal of Applied Electrochemistry, 32 (2002), 12; 1341-1346 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 109793 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Electrochemical study of the chromium electrode behaviour in borate buffer solution
Autori
Marijan, Dražen ; Gojić, Mirko
Izvornik
Journal of Applied Electrochemistry (0021-891X) 32
(2002), 12;
1341-1346
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
capacitor; chromium electrode; chromium passivity; transpassive dissolution
Sažetak
The electrochemical behaviour of the chromium electrode in boorate buffer solution (pH 9.3) was studied by cyclic voltammetry and electrochemical impedance spectroscopy. Chromium passivity was observed over a broad potentila region, from -1.0 to 0.5 V vs. SCE. The passivatin process took place in two steps: formation of a chromium oxide monolayer and transition of chromium to a higher valence state. The anodic film exhibited the properties of a p-type semiconductor. Transpassive dissolution of chromium occured at 0.5 V vs. SCE, with two reaction intermediates present, CrIII and Cr4+
Izvorni jezik
Engleski
Znanstvena područja
Kemijsko inženjerstvo
POVEZANOST RADA
Ustanove:
Fakultet kemijskog inženjerstva i tehnologije, Zagreb
Citiraj ovu publikaciju
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
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