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Pregled bibliografske jedinice broj: 1081607

Photophysical properties and electron transfer photochemical reactivity of substituted phthalimides


Mandić, Leo; Džeba, Iva; Jadreško, Dijana; Mihaljević, Branka; Biczok, Laszlo; Basarić, Nikola
Photophysical properties and electron transfer photochemical reactivity of substituted phthalimides // New journal of chemistry, 44 (2020), 17252-17266 doi:10.1039/D0NJ03465G (međunarodna recenzija, članak, znanstveni)


CROSBI ID: 1081607 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Photophysical properties and electron transfer photochemical reactivity of substituted phthalimides

Autori
Mandić, Leo ; Džeba, Iva ; Jadreško, Dijana ; Mihaljević, Branka ; Biczok, Laszlo ; Basarić, Nikola

Izvornik
New journal of chemistry (1144-0546) 44 (2020); 17252-17266

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
phthalimides ; photodecarboxylation ; photoinduced electron transfer ; photophysics

Sažetak
Photochemical reactivity, photophysical and electrochemical properties for a series of N- adamantylphthalimides bearing carboxylic functional groups were investigated. Upon irradiations (with or without a triplet sensitizer), compounds undergo decarboxylation via a photoinduced electron transfer (PET) from the carboxylate to the phthalimide. UV-Vis and fluorescence pH titrations were used to determine pKa values for the prototropic forms, which were put in connection with quantum yields of the reaction (ΦR). Compounds bearing electron donors OH and OCH3 at the phthalimide 4 position are fluorescent (ΦF = 0.02-0.49) and PET takes place from both singlet and triplet excited states. Estimated rate constants for PET in the singlet excited states for methoxy- and amino-substituted phthalimides are (2.0 ± 0.1) × 109 s-1and (3.4 ± 1.0) × 107 s-1, respectively. Laser flash photolysis (LFP) was conducted to characterize triplet excited states, which are populated less efficiently for compounds with electron donors. The PET is reversible and the overall ΦR depends on the rates for back electron transfer, protonation of the phthalimide radical anion and decarboxylation. Plausible photochemical and photophysical pathways depend on the phthalimide substituents, which is important for the use of phthalimide derivatives in organic synthesis and photocatalysis.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
IP-2014-09-6312 - Supramolekulska kontrola fotokemijskih reakcija eliminacije (SupraPhotoE) (Basarić, Nikola, HRZZ - 2014-09) ( POIROT)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Leo Mandić (autor)

Avatar Url Iva Džeba (autor)

Avatar Url Branka Mihaljević (autor)

Avatar Url Dijana Jadreško (autor)

Avatar Url Nikola Basarić (autor)

Poveznice na cjeloviti tekst rada:

doi pubs.rsc.org doi.org

Citiraj ovu publikaciju:

Mandić, Leo; Džeba, Iva; Jadreško, Dijana; Mihaljević, Branka; Biczok, Laszlo; Basarić, Nikola
Photophysical properties and electron transfer photochemical reactivity of substituted phthalimides // New journal of chemistry, 44 (2020), 17252-17266 doi:10.1039/D0NJ03465G (međunarodna recenzija, članak, znanstveni)
Mandić, L., Džeba, I., Jadreško, D., Mihaljević, B., Biczok, L. & Basarić, N. (2020) Photophysical properties and electron transfer photochemical reactivity of substituted phthalimides. New journal of chemistry, 44, 17252-17266 doi:10.1039/D0NJ03465G.
@article{article, author = {Mandi\'{c}, Leo and D\v{z}eba, Iva and Jadre\v{s}ko, Dijana and Mihaljevi\'{c}, Branka and Biczok, Laszlo and Basari\'{c}, Nikola}, year = {2020}, pages = {17252-17266}, DOI = {10.1039/D0NJ03465G}, keywords = {phthalimides, photodecarboxylation, photoinduced electron transfer, photophysics}, journal = {New journal of chemistry}, doi = {10.1039/D0NJ03465G}, volume = {44}, issn = {1144-0546}, title = {Photophysical properties and electron transfer photochemical reactivity of substituted phthalimides}, keyword = {phthalimides, photodecarboxylation, photoinduced electron transfer, photophysics} }
@article{article, author = {Mandi\'{c}, Leo and D\v{z}eba, Iva and Jadre\v{s}ko, Dijana and Mihaljevi\'{c}, Branka and Biczok, Laszlo and Basari\'{c}, Nikola}, year = {2020}, pages = {17252-17266}, DOI = {10.1039/D0NJ03465G}, keywords = {phthalimides, photodecarboxylation, photoinduced electron transfer, photophysics}, journal = {New journal of chemistry}, doi = {10.1039/D0NJ03465G}, volume = {44}, issn = {1144-0546}, title = {Photophysical properties and electron transfer photochemical reactivity of substituted phthalimides}, keyword = {phthalimides, photodecarboxylation, photoinduced electron transfer, photophysics} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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