Pretražite po imenu i prezimenu autora, mentora, urednika, prevoditelja

Napredna pretraga

Pregled bibliografske jedinice broj: 1081176

Palladium-mediated regioselective C–H bond halogenation of azobenzene substrates by mechanochemistry


Barišić, Dajana; Ćurić, Manda
Palladium-mediated regioselective C–H bond halogenation of azobenzene substrates by mechanochemistry // Adriatic NMR Conference : Book of Abstracts / Bregović, Nikola ; Namjesnik, Danijel ; Novak, Predrag ; Parlov Vuković, Jelena (ur.).
Zagreb: Prirodoslovno-matematički fakultet, Sveučilište u Zagrebu, 2020. str. 28-28 (predavanje, nije recenziran, sažetak, znanstveni)


CROSBI ID: 1081176 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Palladium-mediated regioselective C–H bond halogenation of azobenzene substrates by mechanochemistry

Autori
Barišić, Dajana ; Ćurić, Manda

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Adriatic NMR Conference : Book of Abstracts / Bregović, Nikola ; Namjesnik, Danijel ; Novak, Predrag ; Parlov Vuković, Jelena - Zagreb : Prirodoslovno-matematički fakultet, Sveučilište u Zagrebu, 2020, 28-28

ISBN
978-953-6076-58-1

Skup
Adriatic NMR Conference 2020

Mjesto i datum
Peroj, Hrvatska, 22-24.09.2020

Vrsta sudjelovanja
Predavanje

Vrsta recenzije
Nije recenziran

Ključne riječi
C-H bond halogenation ; azobenzene ; palladium ; mechanochemistry

Sažetak
Development of methods for the direct and selective replacement of inert C–H bond by C–X, C–N, C–S, C–O, or C–C bonds is of immense importance for organic synthesis. The transition metal-catalyzed direct transformations of inactive C–H bond into other functional groups has emerged as a superior approach, which significantly simplifies the synthesis and reduces the generation of byproducts. Currently, these processes still rely predominantly on solvent-based protocols. During the past decade, chemical transformations in the solid-state have become increasingly popular among chemists due to the unique benefits which the solid-state methods provide in terms of sustainability, reaction times, yields, solubility, selectivity, and chemical reactivity. As a continuation of our previous comparative mechanistic study of the mechanochemical C–H bond activation in an unsymmetrical azobenzene by common Pd(II) catalysts, here we present results for palladium-mediated regioselective mechanochemical C–H bond halogenation of azobenzene and its substrates containing electron-donating and electron-withdrawing groups in 4, 4’-positions of azobenzene. Careful selection of liquid and/or solid additives can direct the reaction towards different halogenated products which depend on the electronic properties of substituents, and utilization of ex situ 1H NMR spectroscopy provided detailed insight into the monitored reactions and revealed possible intermediates.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Manda Ćurić (autor)

Avatar Url Dajana Barišić (autor)

Citiraj ovu publikaciju

Barišić, Dajana; Ćurić, Manda
Palladium-mediated regioselective C–H bond halogenation of azobenzene substrates by mechanochemistry // Adriatic NMR Conference : Book of Abstracts / Bregović, Nikola ; Namjesnik, Danijel ; Novak, Predrag ; Parlov Vuković, Jelena (ur.).
Zagreb: Prirodoslovno-matematički fakultet, Sveučilište u Zagrebu, 2020. str. 28-28 (predavanje, nije recenziran, sažetak, znanstveni)
Barišić, D. & Ćurić, M. (2020) Palladium-mediated regioselective C–H bond halogenation of azobenzene substrates by mechanochemistry. U: Bregović, N., Namjesnik, D., Novak, P. & Parlov Vuković, J. (ur.)Adriatic NMR Conference : Book of Abstracts.
@article{article, year = {2020}, pages = {28-28}, keywords = {C-H bond halogenation, azobenzene, palladium, mechanochemistry}, isbn = {978-953-6076-58-1}, title = {Palladium-mediated regioselective C–H bond halogenation of azobenzene substrates by mechanochemistry}, keyword = {C-H bond halogenation, azobenzene, palladium, mechanochemistry}, publisher = {Prirodoslovno-matemati\v{c}ki fakultet, Sveu\v{c}ili\v{s}te u Zagrebu}, publisherplace = {Peroj, Hrvatska} }
@article{article, year = {2020}, pages = {28-28}, keywords = {C-H bond halogenation, azobenzene, palladium, mechanochemistry}, isbn = {978-953-6076-58-1}, title = {Palladium-mediated regioselective C–H bond halogenation of azobenzene substrates by mechanochemistry}, keyword = {C-H bond halogenation, azobenzene, palladium, mechanochemistry}, publisher = {Prirodoslovno-matemati\v{c}ki fakultet, Sveu\v{c}ili\v{s}te u Zagrebu}, publisherplace = {Peroj, Hrvatska} }




Contrast
Increase Font
Decrease Font
Dyslexic Font