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Pregled bibliografske jedinice broj: 1065548

Rapid, clean and scalable synthesis of microporous functional MOFs and their non- conventional forms via mechanochemistry


Užarević, Krunoslav; Karadeniz, Bahar; Stolar, Tomislav; Martinez, Valentina
Rapid, clean and scalable synthesis of microporous functional MOFs and their non- conventional forms via mechanochemistry // CEMWOQ6p5 Program
Montreal, Kanada, 2020. str. 33-33 (predavanje, recenziran, sažetak, ostalo)


CROSBI ID: 1065548 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Rapid, clean and scalable synthesis of microporous functional MOFs and their non- conventional forms via mechanochemistry

Autori
Užarević, Krunoslav ; Karadeniz, Bahar ; Stolar, Tomislav ; Martinez, Valentina

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, ostalo

Izvornik
CEMWOQ6p5 Program / - , 2020, 33-33

Skup
CEMWOQ6p5 (online konferencija)

Mjesto i datum
Montreal, Kanada, 30-31.05.2020

Vrsta sudjelovanja
Predavanje

Vrsta recenzije
Recenziran

Ključne riječi
Mechanochemistry ; non-conventional MOFs ; mixed-metal MOFs ; green synthesis

Sažetak
Porous metal-organic frameworks (MOFs)[1] are one of the most researched areas of modern materials science. These modular materials, whose structure and properties can be readily altered by careful choice of metal nodes and suitable organic linkers, are widely studied for gas storage and separation, catalysis, sensing, light-harvesting, and other applications.[2] The growing number of studies in the field resulted in the recent commercialization of several microporous MOFs on a laboratory scale. However, the standard synthetic procedures, involving an excess of organic solvents and harsh reaction conditions, still prevent their wider industrial application. Here we present the application of mechanochemical reactions, [3] i.e., reactions between solid reactants induced by mechanical force, for a rapid, green and room-temperature transformation of environmentally safe metal precursors, oxides or hydroxides into most relevant microporous MOFs, such as HKUST-1, [4] MOF-74[5] or zirconium-based MOFs of UiO, [6] and NU-[7] families. Mechanochemistry allows even for rapid and efficient synthesis and polymorphic control in complex porphyrinic zirconium MOFs.[8] We show here how the milling produces high-quality zirconium MOFs quantitatively in multigram quantities by using only a catalytic amount of "green" liquids, such as methanol or water.[9]

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
PZS-2019-02-4129
HRZZ-UIP-2014-09-4744 - Mehanokemijska reaktivnost pod kontroliranim uvjetima temperature i atmosfere za čišću sintezu funkcionalnih materijala (MECHANOCONTROL) (Užarević, Krunoslav, HRZZ - 2014-09) ( POIROT)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Citiraj ovu publikaciju

Užarević, Krunoslav; Karadeniz, Bahar; Stolar, Tomislav; Martinez, Valentina
Rapid, clean and scalable synthesis of microporous functional MOFs and their non- conventional forms via mechanochemistry // CEMWOQ6p5 Program
Montreal, Kanada, 2020. str. 33-33 (predavanje, recenziran, sažetak, ostalo)
Užarević, K., Karadeniz, B., Stolar, T. & Martinez, V. (2020) Rapid, clean and scalable synthesis of microporous functional MOFs and their non- conventional forms via mechanochemistry. U: CEMWOQ6p5 Program.
@article{article, year = {2020}, pages = {33-33}, keywords = {Mechanochemistry, non-conventional MOFs, mixed-metal MOFs, green synthesis}, title = {Rapid, clean and scalable synthesis of microporous functional MOFs and their non- conventional forms via mechanochemistry}, keyword = {Mechanochemistry, non-conventional MOFs, mixed-metal MOFs, green synthesis}, publisherplace = {Montreal, Kanada} }
@article{article, year = {2020}, pages = {33-33}, keywords = {Mechanochemistry, non-conventional MOFs, mixed-metal MOFs, green synthesis}, title = {Rapid, clean and scalable synthesis of microporous functional MOFs and their non- conventional forms via mechanochemistry}, keyword = {Mechanochemistry, non-conventional MOFs, mixed-metal MOFs, green synthesis}, publisherplace = {Montreal, Kanada} }




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