Bis-[3] Ferrocenophanes with Central> E- E’< Bonds (E, E’= P, SiH): Preparation, Properties, and Thermal Activation (CROSBI ID 279376)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Isenberg, Stefan ; Weller, Stefan ; Kargin, Denis ; Valić, Srećko ; Schwederski, Brigitte ; Kelemen, Zsolt ; Bruhn, Clemens ; Krekić, Kristijan ; Maurer, Martin ; Feil, Christoph M ; Nieger, Martin ; Gudat, Dietrich ; Nyulászi, László ; Pietschnig, Rudolf
engleski
Bis-[3] Ferrocenophanes with Central> E- E’< Bonds (E, E’= P, SiH): Preparation, Properties, and Thermal Activation
A series of bis-[3]ferrocenophanes of the general type Fe(C5H4E')2E-E(E'C5H4)2Fe (E=P, SiH and E'=PtBu, NneoPentyl, NSi(CH3)3) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X-ray crystallography. The thermal dissociation behavior with respect to homolytic fission of the central bond generating phosphorus centered radicals was investigated using EPR spectroscopy and quantum chemical calculations.
ferrocene ; homolytic bond cleavage ; phosphorus ; radicals ; thermolysis
COST Action 1302
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