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Pregled bibliografske jedinice broj: 1064036

Directing role of the synthetic route on the self-assembly process of MoO42− units to Mo7O242− or Mo22O7416− ions


Kuzman, Dino; Damjanović, Vladimir; Vrdoljak, Višnja; Stilinović, Vladimir; Cindrić, Marina
Directing role of the synthetic route on the self-assembly process of MoO42− units to Mo7O242− or Mo22O7416− ions // Inorganica chimica acta, 510 (2020), 119765, 5 doi:10.1016/j.ica.2020.119765 (međunarodna recenzija, članak, znanstveni)


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Naslov
Directing role of the synthetic route on the self-assembly process of MoO42− units to Mo7O242− or Mo22O7416− ions

Autori
Kuzman, Dino ; Damjanović, Vladimir ; Vrdoljak, Višnja ; Stilinović, Vladimir ; Cindrić, Marina

Izvornik
Inorganica chimica acta (0020-1693) 510 (2020); 119765, 5

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Characterization ; Single crystal X-ray diffraction method ; Mechanochemical synthesis ; Vapour-assisted aging ; Solution based syntheses ; Polyoxomolybdates

Sažetak
Different synthetic routes, solution-based methods performed at room temperature, under reflux or hydrothermally at 110 °C, along with mechanochemically accelerated (hand grinding or liquid-assisted ball milling) vapour-assisted aging, yielded polyoxomolybdate [Co(en)3]2[Mo7O24]·8H2O(1) as the final product. The new heptamolybdate 1 was the only product of the reaction between sodium molybdate, tris(ethylendiamine)cobalt (III) chloride and succinic acid when the used molar ratio of Mo: Co: acid was 1:1:1 or 1:6:1, regardless to the employed synthetic route (solution vs. solid state). From the literature known polyoxomolybdate [Co(en)3]5Na[Mo7O24(μ-Mo8O26)Mo7O24]·nH2O(2) was also isolated as the main product only from the solution based methods where the sodium molybdate was present in an excess (molar ratio 6:1:1) and in the case when the reaction was conducted at elevated temperature and by employing the excess of succinic acid (molar ratio 1:1:6). All products were characterized by means of elemental analysis, IR spectroscopy as well as powder and single crystal X-ray diffraction analysis.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
HRZZ-IP-2016-06-4221 - Metalosupramolekulske strukture i anorgansko-organski polioksometalatni hibridi (MOLART) (Vrdoljak, Višnja, HRZZ - 2016-06) ( POIROT)

Ustanove:
Medicinski fakultet, Zagreb,
Prirodoslovno-matematički fakultet, Zagreb

Citiraj ovu publikaciju

Kuzman, Dino; Damjanović, Vladimir; Vrdoljak, Višnja; Stilinović, Vladimir; Cindrić, Marina
Directing role of the synthetic route on the self-assembly process of MoO42− units to Mo7O242− or Mo22O7416− ions // Inorganica chimica acta, 510 (2020), 119765, 5 doi:10.1016/j.ica.2020.119765 (međunarodna recenzija, članak, znanstveni)
Kuzman, D., Damjanović, V., Vrdoljak, V., Stilinović, V. & Cindrić, M. (2020) Directing role of the synthetic route on the self-assembly process of MoO42− units to Mo7O242− or Mo22O7416− ions. Inorganica chimica acta, 510, 119765, 5 doi:10.1016/j.ica.2020.119765.
@article{article, year = {2020}, pages = {5}, DOI = {10.1016/j.ica.2020.119765}, chapter = {119765}, keywords = {Characterization, Single crystal X-ray diffraction method, Mechanochemical synthesis, Vapour-assisted aging, Solution based syntheses, Polyoxomolybdates}, journal = {Inorganica chimica acta}, doi = {10.1016/j.ica.2020.119765}, volume = {510}, issn = {0020-1693}, title = {Directing role of the synthetic route on the self-assembly process of MoO42− units to Mo7O242− or Mo22O7416− ions}, keyword = {Characterization, Single crystal X-ray diffraction method, Mechanochemical synthesis, Vapour-assisted aging, Solution based syntheses, Polyoxomolybdates}, chapternumber = {119765} }
@article{article, year = {2020}, pages = {5}, DOI = {10.1016/j.ica.2020.119765}, chapter = {119765}, keywords = {Characterization, Single crystal X-ray diffraction method, Mechanochemical synthesis, Vapour-assisted aging, Solution based syntheses, Polyoxomolybdates}, journal = {Inorganica chimica acta}, doi = {10.1016/j.ica.2020.119765}, volume = {510}, issn = {0020-1693}, title = {Directing role of the synthetic route on the self-assembly process of MoO42− units to Mo7O242− or Mo22O7416− ions}, keyword = {Characterization, Single crystal X-ray diffraction method, Mechanochemical synthesis, Vapour-assisted aging, Solution based syntheses, Polyoxomolybdates}, chapternumber = {119765} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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