Direct visualization of a mechanochemically induced molecular rearrangement (CROSBI ID 277844)
Prilog u časopisu | kratko priopćenje | međunarodna recenzija
Podaci o odgovornosti
Ardila-Fierro, Karen J. ; Lukin, Stipe ; Etter, Martin ; Užarević, Krunoslav ; Halasz, Ivan ; Bolm, Carsten ; Hernández, José G.
engleski
Direct visualization of a mechanochemically induced molecular rearrangement
Recent progress in the field of mechanochemistry has expanded the discovery of mechanically induced chemical transformations to several areas of science. However, a general fundamental understanding of how mechanochemical reactions by ball milling occur has remained unreached. For this, we have now implemented in‐situ monitoring of a mechanochemically induced molecular rearrangement by synchrotron X‐ray powder diffraction, Raman spectroscopy, and real‐time temperature sensing. The results of this study demonstrate that molecular rearrangements can be accomplished in the solid- state by ball milling, and how in‐situ monitoring techniques enable the visualization of the changes occurring at the exact instant of a molecular migration. In this study, during the mechanochemical benzil‐benzilic acid rearrangement.
mechanochemistry ; mechanochemical synthesis ; organic synthesis ; molecular rearrangement ; in situ monitoring ; raman spectroscopy ; synchrotron diffraction
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Podaci o izdanju
59 (32)
2020.
13458-13462
objavljeno
1433-7851
1521-3773
10.1002/anie.201914921