Deep eutectic solvents based on betaine and propylene glycol as potential denitrification agents: a liquid-liquid equilibrium study (CROSBI ID 275879)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Rogošić, Marko ; Krišto, Anđela ; Zagajski Kučan, Kristina
engleski
Deep eutectic solvents based on betaine and propylene glycol as potential denitrification agents: a liquid-liquid equilibrium study
Two deep eutectic solvents (DES) based on betaine (B) and propylene glycol (PG) in molar ratios of 1:4 and 1:5 were prepared and their physico- chemical properties were determined. Liquid-liquid equilibria at 298.15 K and atmospheric pressure were determined for 13 quasi-three-component systems with a hydrocarbon (n-hexane, n-heptane, i-octane or toluene), solute (pyridine or thiophene) and DES (B-PG 1:4 or B-PG 1:5). Experimental phase diagrams and calculated distribution ratios showed that DESs are more suitable for denitrification than for desulfurization. The equilibria in the investigated systems were described by the NRTL and UNIQUAC models, and good agreement with experiments was obtained.
deep eutectic solvents ; liquid-liquid equilibrium ; fuel purification ; NRTL ; UNIQUAC
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Podaci o izdanju
36 (4)
2019.
1703-1716
objavljeno
0104-6632
1678-4383
10.1590/0104-6632.20190364s20190049