Pretražite po imenu i prezimenu autora, mentora, urednika, prevoditelja

Napredna pretraga

Pregled bibliografske jedinice broj: 1044777

Reversible Temperature-Stimulated Single- Crystal-to-Single-Crystal Conformational Polymorph Transformation in Cadmium(II) Coordination Trimer with a Water Vapor Sorption/Desorption Potential


Pisačić, Mateja; Kodrin, Ivan; Matijaković, Nives; Chatterjee, Nabanita; Oliver, Clive L.; Kukovec, Boris-Marko; Đaković, Marijana
Reversible Temperature-Stimulated Single- Crystal-to-Single-Crystal Conformational Polymorph Transformation in Cadmium(II) Coordination Trimer with a Water Vapor Sorption/Desorption Potential // Crystal growth & design, 20 (2020), 401-413 doi:10.1021/acs.cgd.9b01322 (međunarodna recenzija, članak, znanstveni)


CROSBI ID: 1044777 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Reversible Temperature-Stimulated Single- Crystal-to-Single-Crystal Conformational Polymorph Transformation in Cadmium(II) Coordination Trimer with a Water Vapor Sorption/Desorption Potential

Autori
Pisačić, Mateja ; Kodrin, Ivan ; Matijaković, Nives ; Chatterjee, Nabanita ; Oliver, Clive L. ; Kukovec, Boris-Marko ; Đaković, Marijana

Izvornik
Crystal growth & design (1528-7483) 20 (2020); 401-413

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
single-crystal-to-single-crystal transformation ; conformational polymorph ; cadmium(II) trimer ; pyridine-4-propanamide ; water sorption/desorption

Sažetak
A crystalline cadmium(II) coordination trimer with pyridine-4-propanamide (4-propy), [Cd3Cl4(H2O)4(4-propy)6](CH3CH2COO)2, readily responds to external stimuli while preserving crystal integrity. Two polymorphic forms, Polymorph-I (triclinic form) and Polymorph-II (monoclinic form), undergo a reversible single- crystal-to-single-crystal conformational polymorph transformation upon temperature change, while the triclinic form (Polymorph-I) additionally shows substantial reversible sorption/desorption potential via two pathways, in response to stimulation by (i) elevated temperature, and (ii) reduced pressure. The elucidation of the conformational transformation via a variety of ex situ and in situ methods (SCXRD, VT-PXRD, TG/DSC and VT- IR), complemented by in-depth theoretical studies, suggested that the conformational transformation might be a process that occurs slowly and continuously over a wider temperature range, with different processes (distinctive conformational changes) taking place over different temperature intervals.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
HRZZ-UIP-2013-11-1809 - Inženjering kristalnih materijala pomoću metalnih kompleksa i nekovalentnih interakcija (CRYSTIN) (Đaković, Marijana, HRZZ - 2013-11) ( POIROT)

Ustanove:
Kemijsko-tehnološki fakultet, Split,
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb

Citiraj ovu publikaciju

Pisačić, Mateja; Kodrin, Ivan; Matijaković, Nives; Chatterjee, Nabanita; Oliver, Clive L.; Kukovec, Boris-Marko; Đaković, Marijana
Reversible Temperature-Stimulated Single- Crystal-to-Single-Crystal Conformational Polymorph Transformation in Cadmium(II) Coordination Trimer with a Water Vapor Sorption/Desorption Potential // Crystal growth & design, 20 (2020), 401-413 doi:10.1021/acs.cgd.9b01322 (međunarodna recenzija, članak, znanstveni)
Pisačić, M., Kodrin, I., Matijaković, N., Chatterjee, N., Oliver, C., Kukovec, B. & Đaković, M. (2020) Reversible Temperature-Stimulated Single- Crystal-to-Single-Crystal Conformational Polymorph Transformation in Cadmium(II) Coordination Trimer with a Water Vapor Sorption/Desorption Potential. Crystal growth & design, 20, 401-413 doi:10.1021/acs.cgd.9b01322.
@article{article, year = {2020}, pages = {401-413}, DOI = {10.1021/acs.cgd.9b01322}, keywords = {single-crystal-to-single-crystal transformation, conformational polymorph, cadmium(II) trimer, pyridine-4-propanamide, water sorption/desorption}, journal = {Crystal growth and design}, doi = {10.1021/acs.cgd.9b01322}, volume = {20}, issn = {1528-7483}, title = {Reversible Temperature-Stimulated Single- Crystal-to-Single-Crystal Conformational Polymorph Transformation in Cadmium(II) Coordination Trimer with a Water Vapor Sorption/Desorption Potential}, keyword = {single-crystal-to-single-crystal transformation, conformational polymorph, cadmium(II) trimer, pyridine-4-propanamide, water sorption/desorption} }
@article{article, year = {2020}, pages = {401-413}, DOI = {10.1021/acs.cgd.9b01322}, keywords = {single-crystal-to-single-crystal transformation, conformational polymorph, cadmium(II) trimer, pyridine-4-propanamide, water sorption/desorption}, journal = {Crystal growth and design}, doi = {10.1021/acs.cgd.9b01322}, volume = {20}, issn = {1528-7483}, title = {Reversible Temperature-Stimulated Single- Crystal-to-Single-Crystal Conformational Polymorph Transformation in Cadmium(II) Coordination Trimer with a Water Vapor Sorption/Desorption Potential}, keyword = {single-crystal-to-single-crystal transformation, conformational polymorph, cadmium(II) trimer, pyridine-4-propanamide, water sorption/desorption} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


Citati





    Contrast
    Increase Font
    Decrease Font
    Dyslexic Font