Direct Mechanocatalysis: Palladium as Milling Media and Catalyst in the Mechanochemical Suzuki Polymerization (CROSBI ID 273778)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Vogt, Christian G. ; Grätz, Sven ; Lukin, Stipe ; Halasz, Ivan ; Etter, Martin ; Evans, Jack D. ; Borchardt, Lars
engleski
Direct Mechanocatalysis: Palladium as Milling Media and Catalyst in the Mechanochemical Suzuki Polymerization
The milling ball is the catalyst. We introduce a palladium-catalyzed reaction inside a ball mill, which makes catalyst powders, ligands, and solvents obsolete. We present a facile and highly sustainable synthesis concept for palladium-catalyzed C-C coupling reactions, exemplarily showcased for the Suzuki polymerization of 4-bromo or 4iodophenylboronic acid giving poly(para-phenylene). Surprisingly, we observe one of the highest degrees of polymerization (199) reported so far.
heterogeneous catalysis ; mechanochemistry ; poly(para-phenylene) ; sustainable chemistry ; Suzuki cross-coupling
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Podaci o izdanju
58 (52)
2019.
18942-18947
objavljeno
1433-7851
1521-3773
10.1002/anie.201911356