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Pregled bibliografske jedinice broj: 10374

Temperature determination of transient species by DFWM: Application of the independently determined power law of the transition dipole moment and geometric factors


Lehr, L.; Motzkus, M.; Pichler, Goran; Kompa, K. L.; Hering, P.
Temperature determination of transient species by DFWM: Application of the independently determined power law of the transition dipole moment and geometric factors // The Journal of chemical physics, 104 (1996), 24; 9698-9703 (međunarodna recenzija, članak, znanstveni)


Naslov
Temperature determination of transient species by DFWM: Application of the independently determined power law of the transition dipole moment and geometric factors

Autori
Lehr, L. ; Motzkus, M. ; Pichler, Goran ; Kompa, K. L. ; Hering, P.

Izvornik
The Journal of chemical physics (0021-9606) 104 (1996), 24; 9698-9703

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Temperature determination; transient species; NaH

Sažetak
We investigated the dependence of the Degenerate Four Wave Mixing (DFWM) signal intensities on the electronic transition dipole moment of isolated lines in the transition band of NaH. We applied a new way to determine this dependence in transient species without previous knowledge of the sample temperature. By using different appropriate pairs of DFWM lines sharing common lower level the relative population difference is eliminated. We found that this ratio is well described by a power law (ľ1/ľ2)x where ľi is the electronic one-photon transition dipole moment. As a result of saturation the exponent x depends on the total laser energy deposited in the medium. The observations are in good agreement with a modified two-level model, which includes the effects of polarization of the laser beams due to the used experimental setup by introducing geometric factors. The exponent of the integrated signal intensities varies between 3 and 8 for high and low laser intensities with a rapid decrease to high intensities. Therefore it is now possible to compare signal intensities at different DFWM laser intensities in order to obtain relative level populations, i.e. temperature, with high sensitivity.

Izvorni jezik
Engleski

Znanstvena područja
Fizika



POVEZANOST RADA


Projekt / tema
00350102

Ustanove
Institut za fiziku, Zagreb

Autor s matičnim brojem:
Goran Pichler, (37152)

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus