Building organosilica hybrid nanohemispheres via thiol-ene click reaction on alumina thin films deposited by atomic layer deposition (ALD) (CROSBI ID 270911)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Ambrožić, Gabriela ; Kolympadi Markovic, Maria ; Peter, Robert ; Kavre Piltaver, Ivna ; Jelovica Badovinac, Ivana ; Čakara, Duško ; Marković, Dean ; Knez, Mato
engleski
Building organosilica hybrid nanohemispheres via thiol-ene click reaction on alumina thin films deposited by atomic layer deposition (ALD)
The present work shows a surface-induced preparation of sub-100 nm organosilica nanohemispheres on atomic layer deposited (ALD) Al2O3 thin films, which was achieved by cooperative condensation/hydrolysis and thiol- ene click chemical reactions. The two-step synthetic approach consists of an initial silanization of the Al2O3 film with vinyltrimethoxysilane (VTMS), followed by a photo-promoted growth of surface-bound nanoparticles in the presence of (3- mercaptopropyl)trimethoxysilane (MPTMS). Characterization by means of FE-SEM, XPS and EDS points towards the growth of the nanohemispherical structures being governed by an initial nucleation of thiolated organosilica seeds in solution as a result of self- condensation of MPTMS and oxidation of thiols to disulfides. Once bound to the vinyl terminated Al2O3 via photo-assisted thiol-ene coupling, these seeds promote area-selective growth of the nanoparticles through binding of further MPTMS from the solution. After an additional ALD deposition of ZnO, the resulting thin hybrid film exhibits enhanced hydrophobicity when compared to ZnO films deposited directly on Al2O3 under the same processing conditions.
Organosilica hybrids ; Nanohemispheres ; Thiol-ene reaction ; Thin films ; Atomic layer deposition ; Al2O3 ; ZnO
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Podaci o izdanju
560
2020.
303-311
objavljeno
0021-9797
1095-7103
10.1016/j.jcis.2019.10.074
Povezanost rada
Interdisciplinarne prirodne znanosti, Kemija