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Pregled bibliografske jedinice broj: 1032583

Building organosilica hybrid nanohemispheres via thiol-ene click reaction on alumina thin films deposited by atomic layer deposition (ALD)


Ambrožić, Gabriela; Kolympadi Markovic, Maria; Peter, Robert; Kavre Piltaver, Ivna; Jelovica Badovinac, Ivana; Čakara, Duško; Marković, Dean; Knez, Mato
Building organosilica hybrid nanohemispheres via thiol-ene click reaction on alumina thin films deposited by atomic layer deposition (ALD) // Journal of Colloid and Interface Science, 560 (2020), 303-311 doi:10.1016/j.jcis.2019.10.074 (međunarodna recenzija, članak, znanstveni)


Naslov
Building organosilica hybrid nanohemispheres via thiol-ene click reaction on alumina thin films deposited by atomic layer deposition (ALD)

Autori
Ambrožić, Gabriela ; Kolympadi Markovic, Maria ; Peter, Robert ; Kavre Piltaver, Ivna ; Jelovica Badovinac, Ivana ; Čakara, Duško ; Marković, Dean ; Knez, Mato

Izvornik
Journal of Colloid and Interface Science (0021-9797) 560 (2020); 303-311

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Organosilica hybrids Nanohemispheres Thiol-ene reaction Thin films Atomic layer deposition Al2O3 ZnO

Sažetak
The present work shows a surface-induced preparation of sub-100 nm organosilica nanohemispheres on atomic layer deposited (ALD) Al2O3 thin films, which was achieved by cooperative condensation/hydrolysis and thiol-ene click chemical reactions. The two-step synthetic approach consists of an initial silanization of the Al2O3 film with vinyltrimethoxysilane (VTMS), followed by a photo-promoted growth of surface-bound nanoparticles in the presence of (3-mercaptopropyl)trimethoxysilane (MPTMS). Characterization by means of FE-SEM, XPS and EDS points towards the growth of the nanohemispherical structures being governed by an initial nucleation of thiolated organosilica seeds in solution as a result of self-condensation of MPTMS and oxidation of thiols to disulfides. Once bound to the vinyl terminated Al2O3 via photo-assisted thiol-ene coupling, these seeds promote area-selective growth of the nanoparticles through binding of further MPTMS from the solution. After an additional ALD deposition of ZnO, the resulting thin hybrid film exhibits enhanced hydrophobicity when compared to ZnO films deposited directly on Al2O3 under the same processing conditions.

Izvorni jezik
Engleski



POVEZANOST RADA


Citiraj ovu publikaciju

Ambrožić, Gabriela; Kolympadi Markovic, Maria; Peter, Robert; Kavre Piltaver, Ivna; Jelovica Badovinac, Ivana; Čakara, Duško; Marković, Dean; Knez, Mato
Building organosilica hybrid nanohemispheres via thiol-ene click reaction on alumina thin films deposited by atomic layer deposition (ALD) // Journal of Colloid and Interface Science, 560 (2020), 303-311 doi:10.1016/j.jcis.2019.10.074 (međunarodna recenzija, članak, znanstveni)
Ambrožić, G., Kolympadi Markovic, M., Peter, R., Kavre Piltaver, I., Jelovica Badovinac, I., Čakara, D., Marković, D. & Knez, M. (2020) Building organosilica hybrid nanohemispheres via thiol-ene click reaction on alumina thin films deposited by atomic layer deposition (ALD). Journal of Colloid and Interface Science, 560, 303-311 doi:10.1016/j.jcis.2019.10.074.
@article{article, year = {2020}, pages = {303-311}, DOI = {10.1016/j.jcis.2019.10.074}, keywords = {Organosilica hybrids Nanohemispheres Thiol-ene reaction Thin films Atomic layer deposition Al2O3 ZnO}, journal = {Journal of Colloid and Interface Science}, doi = {10.1016/j.jcis.2019.10.074}, volume = {560}, issn = {0021-9797}, title = {Building organosilica hybrid nanohemispheres via thiol-ene click reaction on alumina thin films deposited by atomic layer deposition (ALD)}, keyword = {Organosilica hybrids Nanohemispheres Thiol-ene reaction Thin films Atomic layer deposition Al2O3 ZnO} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
  • Scopus
  • MEDLINE


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