engleski

Metal-Hydride Organic Frameworks : synthesis and structure

Metal-hydride organic frameworks (HOF) are a novel hybrid materials designed by combining molecular building blocks of light-weight complex hydrides with organic linkers developed for coordination frameworks. They will be based on crystal engineering principles of coordination frameworks and have new properties (guest-host interactions, dehydrogenation properties) defined by the nature of the unique complex-hydride ligands. HOFs present new type of frameworks due to coordination than usually available in coordination frameworks.

mechanochemical synthesis ; tetrahydridoborates ; hybrid metal-organic frameworks ; imidazolate ; X-ray powder diffraction ; synchrotron radiation ; crystal structure determination

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