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Pregled bibliografske jedinice broj: 1030939

Low-cost synthesis of Cu-modified immobilized nanoporous TiO2 for photocatalytic degradation of 1H-benzotriazole


Čižmar, Tihana; Panžić, Ivana; Salamon, Krešimir; Grčić, Ivana; Radetić, Lucija; Marčec, Jan; Gajović, Andreja
Low-cost synthesis of Cu-modified immobilized nanoporous TiO2 for photocatalytic degradation of 1H-benzotriazole // Catalysts (2019) (znanstveni, poslan)


Naslov
Low-cost synthesis of Cu-modified immobilized nanoporous TiO2 for photocatalytic degradation of 1H-benzotriazole

Autori
Čižmar, Tihana ; Panžić, Ivana ; Salamon, Krešimir ; Grčić, Ivana ; Radetić, Lucija ; Marčec, Jan ; Gajović, Andreja

Vrsta, podvrsta
Radovi u časopisima, znanstveni

Izvornik
Catalysts (2019)

Status rada
Poslan

Ključne riječi
Immobilized nanoporous TiO2 ; electrochemical anodization ; Cu-modification ; photocatalytic activity ; spin-coating ; 1H-benzotriazole

Sažetak
Cu-modification of immobilised nanoporous TiO2 photocatalysts, prepared by electrochemical anodization of titanium foils, were obtained via three different synthesis methods: hydrothermal synthesis, electrodeposition and spin-coating, using two different copper sources, Cu(NO3)2 and Cu(acac)2. Objective of this research was to investigate how copper modifications can improve the photocatalytic activity of immobilised nanoporous TiO2 under the UV/solar light irradiation. The best photocatalytic performances were obtained for Cu-modifications using spin coating. Therefore, the effect of irradiated catalyst surface size on the adsorption of model pollutants, methylene blue (MB) and 1H-benzotriazole (BT), was examined for samples with Cu-modification by spin-coating technique. The mechanisms responsible for increased degradation of MB and BT at high Cu concentrations (0.25 M and 0.5 M) and decreased degradation at low Cu loadings (0.0625 M and 0.125 M) were explained. 1H- benzotriazole was used to study photocatalytic activity of the given samples because it is highly toxic and present in most water systems. Characterization of the synthesized Cu-modified photocatalysts in the terms of phase composition, crystal structure and morphology was examined using X-ray Diffraction, Raman Spectroscopy, Scanning Electron Microscopy and Energy Dispersive X-ray spectroscopy.

Izvorni jezik
Engleski

Znanstvena područja
Fizika, Kemija



POVEZANOST RADA


Projekt / tema
IP-2018-01-5246

Ustanove
Institut "Ruđer Bošković", Zagreb,
Geotehnički fakultet, Varaždin

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus