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Pregled bibliografske jedinice broj: 1030410

Facile Mechanochemical Anion Substitution in Cyclopalladated Azo-benzenes


Bjelopetrović, Alen; Robić; Marko, Halasz, Ivan; Babić, Darko; Juribašić Kulcsar, Marina; Ćurić, Manda
Facile Mechanochemical Anion Substitution in Cyclopalladated Azo-benzenes // Organometallics, 38 (2019), 22; 4479-4484 doi:10.1021/acs.organomet.9b00626 (međunarodna recenzija, članak, znanstveni)


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Naslov
Facile Mechanochemical Anion Substitution in Cyclopalladated Azo-benzenes

Autori
Bjelopetrović, Alen ; Robić ; Marko, Halasz, Ivan ; Babić, Darko ; Juribašić Kulcsar, Marina ; Ćurić, Manda

Izvornik
Organometallics (0276-7333) 38 (2019), 22; 4479-4484

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
solvent-free ; anion substitution ; organopalladium compounds ; cyclopaladates ; azobenzenes ; mechanochemistry

Sažetak
Solvent-free ball-milling method for substitution of anionic ligands in organopalladium compounds was developed. Reactions of acetate, acetylacetonate, chloride or tetrafluoroborate of mono- or dicyclopalladated azobenzenes with alkali salts of chloride acetate and acetylacetonate yielded target products, some of which could not be obtained via direct C–H bond activation by Pd(II) precursors. The formation of products was monitored in situ by Raman spectroscopy and ex situ by NMR and IR spectroscopies and PXRD. The reported solid-state pathway provides an easy access to organopalladium derivatives in high yields and in shorter reaction times than solvent-based protocols.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
HRZZ-IP-2014-09-7984 - Zelena sinteza organopaladijevih foto-osjetljivih spojeva

Ustanove
Institut "Ruđer Bošković", Zagreb

Citiraj ovu publikaciju

Bjelopetrović, Alen; Robić; Marko, Halasz, Ivan; Babić, Darko; Juribašić Kulcsar, Marina; Ćurić, Manda
Facile Mechanochemical Anion Substitution in Cyclopalladated Azo-benzenes // Organometallics, 38 (2019), 22; 4479-4484 doi:10.1021/acs.organomet.9b00626 (međunarodna recenzija, članak, znanstveni)
Bjelopetrović, A., Robić, Marko, Halasz, Ivan, Babić, D., Juribašić Kulcsar, M. & Ćurić, M. (2019) Facile Mechanochemical Anion Substitution in Cyclopalladated Azo-benzenes. Organometallics, 38 (22), 4479-4484 doi:10.1021/acs.organomet.9b00626.
@article{article, year = {2019}, pages = {4479-4484}, DOI = {10.1021/acs.organomet.9b00626}, keywords = {solvent-free, anion substitution, organopalladium compounds, cyclopaladates, azobenzenes, mechanochemistry}, journal = {Organometallics}, doi = {10.1021/acs.organomet.9b00626}, volume = {38}, number = {22}, issn = {0276-7333}, title = {Facile Mechanochemical Anion Substitution in Cyclopalladated Azo-benzenes}, keyword = {solvent-free, anion substitution, organopalladium compounds, cyclopaladates, azobenzenes, mechanochemistry} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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