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Pregled bibliografske jedinice broj: 1029735

Sandwich-type Inorganic–Organic Hybrid Solids of Iso-polyvanadate Clusters and Decamethylcucurbit[5]uril


Han, Li-Wei; Lin, Jing-Xiang; Yin, Qi; Karadeniz, Bahar; Li, Hong-Fang; Lü, Jian; Cao, Rong
Sandwich-type Inorganic–Organic Hybrid Solids of Iso-polyvanadate Clusters and Decamethylcucurbit[5]uril // Crystal growth & design, 16 (2016), 3; 1213-1217 doi:10.1021/acs.cgd.5b01176 (međunarodna recenzija, članak, znanstveni)


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Naslov
Sandwich-type Inorganic–Organic Hybrid Solids of Iso-polyvanadate Clusters and Decamethylcucurbit[5]uril

Autori
Han, Li-Wei ; Lin, Jing-Xiang ; Yin, Qi ; Karadeniz, Bahar ; Li, Hong-Fang ; Lü, Jian ; Cao, Rong

Izvornik
Crystal growth & design (1528-7483) 16 (2016), 3; 1213-1217

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Inorganic-Organic Hybrid ; Polyoxometalate

Sažetak
Three sandwich-type inorganic–organic hybrid solids based on iso-polyvanadate cluster, {; ; V4O12}; ; 4–, {; ; H2V6O18}; ; 4–, or {; ; H2V10O28}; ; 4–, and decamethylcucurbit[5]uril (Me10CB[5]) have been synthesized under hydrothermal conditions. In the structures of (NH4)4[(V4O12)·(Me10CB[5]@0.5H2O)2]·∼15H2O (1) and (NH4)4[(H2V10O28)·(Me10CB[5]@H2O)2]·∼16H2O (3), tetranuclear {; ; V4O12}; ; 4– or decanuclear {; ; H2V10O28}; ; 4– clusters are sandwiched by (NH4)2@Me10CB[5] closed molecular capsules, through hydrogen-bonding interactions, whereas compound 2, formulated as Li4(H2O)6[(H2V6O18)·(Me10CB[5]@H2O)2]·∼14H2O, is built by hexanuclear {; ; H2V6O18}; ; 4– clusters that are covalently sandwiched by Li2@Me10CB[5] half-open molecular capsules in a way similar to thoset of 1 and 3. Compounds 1–3 represent rare examples of sandwich-type polyoxometalate (POM)-based materials in which POM units are inserted at the inner sphere by either hydrogen or covalent bonds. Compound 2 has shown rational photocatalytic activity toward the degradation of methyl orange solutions under visible light.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Ustanove
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Bahar Karadeniz (autor)

Citiraj ovu publikaciju

Han, Li-Wei; Lin, Jing-Xiang; Yin, Qi; Karadeniz, Bahar; Li, Hong-Fang; Lü, Jian; Cao, Rong
Sandwich-type Inorganic–Organic Hybrid Solids of Iso-polyvanadate Clusters and Decamethylcucurbit[5]uril // Crystal growth & design, 16 (2016), 3; 1213-1217 doi:10.1021/acs.cgd.5b01176 (međunarodna recenzija, članak, znanstveni)
Han, L., Lin, J., Yin, Q., Karadeniz, B., Li, H., Lü, J. & Cao, R. (2016) Sandwich-type Inorganic–Organic Hybrid Solids of Iso-polyvanadate Clusters and Decamethylcucurbit[5]uril. Crystal growth & design, 16 (3), 1213-1217 doi:10.1021/acs.cgd.5b01176.
@article{article, year = {2016}, pages = {1213-1217}, DOI = {10.1021/acs.cgd.5b01176}, keywords = {Inorganic-Organic Hybrid, Polyoxometalate}, journal = {Crystal growth and design}, doi = {10.1021/acs.cgd.5b01176}, volume = {16}, number = {3}, issn = {1528-7483}, title = {Sandwich-type Inorganic–Organic Hybrid Solids of Iso-polyvanadate Clusters and Decamethylcucurbit[5]uril}, keyword = {Inorganic-Organic Hybrid, Polyoxometalate} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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