Structural and topological regulation on cobalt coordination polymers with mixed ligands (CROSBI ID 270325)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Cao, Hai-Lei ; Cai, Feng-Ying ; Han, Li-Wei ; Karadeniz, Bahar ; Lu, Jian
engleski
Structural and topological regulation on cobalt coordination polymers with mixed ligands
Structural and topological regulation on a series of cobalt coordination polymers (CPs) built by V-shaped O-donor ligand, 4, 4′- (hexafluoroisopropylidene)-bis(benzoic acid) (H2L), and auxiliary N-donor ligands was reported. The introduction of secondary N-donor ligands (2, 2′-bipyridine, BPY ; 1, 3-bis(4- pyridyl)propane, BPP) greatly affected the overall structures of cobalt CPs, due to the structural taloring/directing effect of the neutral coordinating molecules BPY and BPP. The CPs were characterized by single crystal X-ray diffractions, infrared spectroscopy, thermogravimetry measurements, elemental analyses and X-ray powder diffractions. X-ray crystallography suggested the CPs possess 2-D covalent network structures, which identified versatile underlying topological structures. Moreover, magnetic properties of two complexes were also explored.
Cobalt ; Coordination Polymer ; Topology ; Magnetism
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Podaci o izdanju
85
2017.
5-8
objavljeno
1387-7003
1879-0259
10.1016/j.inoche.2017.04.024
Povezanost rada
Kemija