Pretražite po imenu i prezimenu autora, mentora, urednika, prevoditelja

Napredna pretraga

Pregled bibliografske jedinice broj: 1026829

Single- and Bimetallic Amidoboranes - Solid-State Synthesis and Decomposition


Biliškov, Nikola; Milanović, Igor; Halasz, Ivan
Single- and Bimetallic Amidoboranes - Solid-State Synthesis and Decomposition // Science and educational challenges facing Europe in the next decade : book of abstract / Ivanda, Mile ; Skenderović, Hrvoje (ur.).
Zagreb: Alexander von Humboldt Stiftung, 2019. str. 29-29 (poster, domaća recenzija, sažetak, znanstveni)


CROSBI ID: 1026829 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Single- and Bimetallic Amidoboranes - Solid-State Synthesis and Decomposition

Autori
Biliškov, Nikola ; Milanović, Igor ; Halasz, Ivan

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Science and educational challenges facing Europe in the next decade : book of abstract / Ivanda, Mile ; Skenderović, Hrvoje - Zagreb : Alexander von Humboldt Stiftung, 2019, 29-29

ISBN
978-953-97333-6-8

Skup
Science and educational challenges facing Europe in the next decade

Mjesto i datum
Zagreb, Hrvatska, 10.-11.10.2019

Vrsta sudjelovanja
Poster

Vrsta recenzije
Domaća recenzija

Ključne riječi
Ammonia borane ; amidoboranes ; ball milling ; mechanochemistry ; XRD ; IR spectroscopy ; Hydrides ; hydrogen storage

Sažetak
Amidoboranes, a family of B, N-containing compounds that are under a vivid consideration as potential chemical hydrogen containers, can be readily prepared by ball milling from ammonia borane and corresponding hydride(s). However, details of the mechanistic pathways toward these materials are still not satisfactory recovered. By recovering the intermediates and other crucial elements of the synthesis, in-situ and real-time monitoring, by means of Raman spectroscopy and powder XRD, of uninterrupted mechanochemical preparations provides a unique insight into the mechanistic pathways. Here we illustrate the application of these techniques to preparation of several single- and bimetallic amidoboranes. This approach allowed realtime observation of key intermediate phases and a straightforward follow-up of the progress of the reaction, thus enabling a detailed interpretation of mechanistic pathways. On the other hand, from the application point of view, it is crucially important to recover the mechanisms of solid-state thermally-induced decomposition of the obtained amidoboranes. Again, a number of techniques that enable in-situ monitoring of the relevant processes are applied. Here, these efforts will be presented, together with our ongoing results.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
HRZZ-PKP-2016-06-4480 - Novi materijali za pohranu energije (NEWMATENG) (Halasz, Ivan, HRZZ - 2016-06) ( POIROT)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Ivan Halasz (autor)

Avatar Url Nikola Biliškov (autor)

Avatar Url Igor Milanović (autor)


Citiraj ovu publikaciju

Biliškov, Nikola; Milanović, Igor; Halasz, Ivan
Single- and Bimetallic Amidoboranes - Solid-State Synthesis and Decomposition // Science and educational challenges facing Europe in the next decade : book of abstract / Ivanda, Mile ; Skenderović, Hrvoje (ur.).
Zagreb: Alexander von Humboldt Stiftung, 2019. str. 29-29 (poster, domaća recenzija, sažetak, znanstveni)
Biliškov, N., Milanović, I. & Halasz, I. (2019) Single- and Bimetallic Amidoboranes - Solid-State Synthesis and Decomposition. U: Ivanda, M. & Skenderović, H. (ur.)Science and educational challenges facing Europe in the next decade : book of abstract.
@article{article, year = {2019}, pages = {29-29}, keywords = {Ammonia borane, amidoboranes, ball milling, mechanochemistry, XRD, IR spectroscopy, Hydrides, hydrogen storage}, isbn = {978-953-97333-6-8}, title = {Single- and Bimetallic Amidoboranes - Solid-State Synthesis and Decomposition}, keyword = {Ammonia borane, amidoboranes, ball milling, mechanochemistry, XRD, IR spectroscopy, Hydrides, hydrogen storage}, publisher = {Alexander von Humboldt Stiftung}, publisherplace = {Zagreb, Hrvatska} }
@article{article, year = {2019}, pages = {29-29}, keywords = {Ammonia borane, amidoboranes, ball milling, mechanochemistry, XRD, IR spectroscopy, Hydrides, hydrogen storage}, isbn = {978-953-97333-6-8}, title = {Single- and Bimetallic Amidoboranes - Solid-State Synthesis and Decomposition}, keyword = {Ammonia borane, amidoboranes, ball milling, mechanochemistry, XRD, IR spectroscopy, Hydrides, hydrogen storage}, publisher = {Alexander von Humboldt Stiftung}, publisherplace = {Zagreb, Hrvatska} }




Contrast
Increase Font
Decrease Font
Dyslexic Font