Rational Synthesis of Mixed-Metal Microporous Metal–Organic Frameworks with Controlled Composition Using Mechanochemistry (CROSBI ID 269085)
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Podaci o odgovornosti
Ayoub, Ghada ; Karadeniz, Bahar ; Howarth, Ashlee J. ; Farha, Omar K. ; Đilović, Ivica ; Germann, Luzia S. ; Dinnebier, Robert E. ; Užarević, Krunoslav ; Friščić, Tomislav
engleski
Rational Synthesis of Mixed-Metal Microporous Metal–Organic Frameworks with Controlled Composition Using Mechanochemistry
Mechanochemistry enables targeted, rapid synthesis of bimetallic metal−organic frameworks (MOFs) with a controlled 1:1 stoichiometric composition of metal nodes. In particular, ball milling enabled the use of specifically synthesized solid coordination complexes of Zn(II), Mg(II), Ni(II), and Co(II) for the assembly of a range of microporous mixed-metal MOF-74 materials composed of pairs of d-block or main group metals in a predetermined 1:1 stoichiometric ratio, including ZnMg-, ZnCo-, ZnCu-, MgZn-, MgCo-, NiZn-, NiMg-, NiCo-, CoZn-, CoMg-, CoCu-, and MgCa-MOF-74. By using specifically prepared precursors in the ynthesis of diverse mixed-metal MOF-74 targets, this rational synthesis represents the first entry of mechanochemistry into the target-oriented synthesis of mixed- metal MOFs.
Mechanochemistry ; MOF-74 ; mixed-metal MOFs ; green synthesis
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Podaci o izdanju
31 (15)
2019.
5494-5501
objavljeno
0897-4756
1520-5002
10.1021/acs.chemmater.9b01068