engleski

Carbon-13 chemical shifts of inverted carbon atoms

The inverted carbons in 2, 4-methano-2, 4-dehydroadamantane are shielded by 14.3 ppm relative to the corresponding carbons in 2, 4-methanoadamantane. This was explained by the balance of the inverted carbon hybridization deshielding, the shielding effect of the cyclopropane rings formed, and the change in the influence of the neighbouring atoms.

2, 4-methano-2 ; 4-dehydroadamantane ; inverted carbon

nije evidentirano