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Pregled bibliografske jedinice broj: 1012145

Vapor and thermally induced solid-state structural transformations


Mandarić, Mirna; Vrdoljak, Višnja
Vapor and thermally induced solid-state structural transformations // SCIRES 2019: Book of Abstracts / Biliškov, Nikola (ur.).
Zagreb: Institut Ruđer Bošković, 2019. str. 91-91 (poster, međunarodna recenzija, sažetak, znanstveni)


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Naslov
Vapor and thermally induced solid-state structural transformations

Autori
Mandarić, Mirna ; Vrdoljak, Višnja

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
SCIRES 2019: Book of Abstracts / Biliškov, Nikola - Zagreb : Institut Ruđer Bošković, 2019, 91-91

ISBN
978-953-7941-32-1

Skup
Solid-State Science & Research Meeting 2019

Mjesto i datum
Zagreb, Hrvatska, 27-29.06.2019

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
molybdenum(VI) complexes ; hydrazone ; vapour and thermally induced structural transformations ; SC-SC transformations

Sažetak
Reactions or structural transformations in the solid-state are more difficult than in solution because they involve new bond formation or breakage with restricted molecular movements. [1] Synthesis of the mononuclear complex was carried out by using bis(pentane-2, 4- dionato)dioxomolybdenum(VI) and 4- methoxysalicylaldehyde isonicotinoyl hydrazine. The mononuclear complex was used as a precursor for structural transformations in the solid state (Figure 1). Crystals of [MoO2(L)(MeOH)] were exposed to organic solvent vapors. Also, thermally-induced transformations were investigated. These reactions resulted in the formation of the coordination polymer [MoO2(L)]n. When [MoO2(L)(MeOH)] was exposed to water vapor the coordinated MeOH ligand were replaced with H2O. These transformations occured in a SC-SC manner.[2]

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
HRZZ-IP-2016-06-4221 - Metalosupramolekulske strukture i anorgansko-organski polioksometalatni hibridi (MOLART) (Vrdoljak, Višnja, HRZZ - 2016-06) ( POIROT)

Ustanove:
Prirodoslovno-matematički fakultet, Zagreb

Profili:

Avatar Url Višnja Vrdoljak (autor)

Avatar Url Mirna Mandarić (autor)


Citiraj ovu publikaciju

Mandarić, Mirna; Vrdoljak, Višnja
Vapor and thermally induced solid-state structural transformations // SCIRES 2019: Book of Abstracts / Biliškov, Nikola (ur.).
Zagreb: Institut Ruđer Bošković, 2019. str. 91-91 (poster, međunarodna recenzija, sažetak, znanstveni)
Mandarić, M. & Vrdoljak, V. (2019) Vapor and thermally induced solid-state structural transformations. U: Biliškov, N. (ur.)SCIRES 2019: Book of Abstracts.
@article{article, editor = {Bili\v{s}kov, N.}, year = {2019}, pages = {91-91}, keywords = {molybdenum(VI) complexes, hydrazone, vapour and thermally induced structural transformations, SC-SC transformations}, isbn = {978-953-7941-32-1}, title = {Vapor and thermally induced solid-state structural transformations}, keyword = {molybdenum(VI) complexes, hydrazone, vapour and thermally induced structural transformations, SC-SC transformations}, publisher = {Institut Ru\djer Bo\v{s}kovi\'{c}}, publisherplace = {Zagreb, Hrvatska} }
@article{article, editor = {Bili\v{s}kov, N.}, year = {2019}, pages = {91-91}, keywords = {molybdenum(VI) complexes, hydrazone, vapour and thermally induced structural transformations, SC-SC transformations}, isbn = {978-953-7941-32-1}, title = {Vapor and thermally induced solid-state structural transformations}, keyword = {molybdenum(VI) complexes, hydrazone, vapour and thermally induced structural transformations, SC-SC transformations}, publisher = {Institut Ru\djer Bo\v{s}kovi\'{c}}, publisherplace = {Zagreb, Hrvatska} }




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