Activation of C–H Bond in Benzo[h]quinoline with Various PdII Precursors (CROSBI ID 678168)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | međunarodna recenzija
Podaci o odgovornosti
Barišić, Dajana ; Juribašić Kulcsar, Marina ; Ćurić, Manda
engleski
Activation of C–H Bond in Benzo[h]quinoline with Various PdII Precursors
Activation of unreactive C–H bonds with PdII precursors is the most common method for the preparation of organopalladium compounds, known as palladacycles, and it is the key step in many catalytic reactions induced by palladium catalysts. These processes mainly rely on solvent-based protocols, which may require toxic solvents and are often long lasting. Recent advances in performing chemical transformations under milling conditions resulted in the first mechanosynthesis of palladacycles via C–H bond(s) activation. This synthesis promptly led to the use of ball milling methods in the metal-catalyzed functionalization of organic molecules, followed by the first comparative mechanistic study on the regioselective mechanochemical C–H bond activation in an unsymmetrical azobenzene substrate by the most common PdII catalysts, using liquid and/or solid additives. Within this work, the reactivity trend found for the PdII catalytic precursors in above-described reactions ([Pd(OAc)2]3 < PdCl2 < [Pd(MeCN)4[BF4]2) was tested in their reactions with benzo[h]quinoline which contains only one C–H bond for directed C–H activation in contrast to the 4, 4’-substituted azobenzenes (Scheme 1).
C-H bond activation ; benzo[h]quinoline ; palladium ; mechanochemistry
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Podaci o prilogu
120-120.
2019.
objavljeno
Podaci o matičnoj publikaciji
Solid-State Science & Research Meeting 2019 - Book of Abstracts
Biliškov, Nikola
Zagreb: Institut Ruđer Bošković
978-953-7941-32-1
Podaci o skupu
Solid State Science and Research Meeting
poster
27.06.2019-29.06.2019
Zagreb, Hrvatska