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Pregled bibliografske jedinice broj: 1007485

Covalent modification of MWCNT with quaternary ammonium groups


Ravnjak, Gabriela; Dandić, Andrea; Budetić, Mateja; Samardžić, Mirela; Sečenji, Aleksandar
Covalent modification of MWCNT with quaternary ammonium groups // 26. hrvatski skup kemičara i kemijskih inženjera s međunarodnim sudjelovanjem 4. simpozij Vladimir Prelog Knjiga sažetaka / Galić, Nives ; Rogošić, Marko (ur.).
Zagreb, 2019. str. 58-58 (poster, recenziran, sažetak, znanstveni)


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Naslov
Covalent modification of MWCNT with quaternary ammonium groups

Autori
Ravnjak, Gabriela ; Dandić, Andrea ; Budetić, Mateja ; Samardžić, Mirela ; Sečenji, Aleksandar

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
26. hrvatski skup kemičara i kemijskih inženjera s međunarodnim sudjelovanjem 4. simpozij Vladimir Prelog Knjiga sažetaka / Galić, Nives ; Rogošić, Marko - Zagreb, 2019, 58-58

ISBN
978-953-6894-67-3

Skup
26. hrvatski skup kemičara i kemijskih inženjera s međunarodnim sudjelovanjem 4. simpozij Vladimir Prelog

Mjesto i datum
Šibenik, Hrvatska, 09-12.04.2019

Vrsta sudjelovanja
Poster

Vrsta recenzije
Recenziran

Ključne riječi
multi walled carbon nanotubes ; covalent modification ; quaternary ammonium groups

Sažetak
Since their discovery, carbon nanotubes (CNT) have been found to be a promising material for various applications because of their unique properties like electric conductivity, mechanical strength and chemical stability. Some of the most explored fields of applications are electronics, drug delivery, composite material production, catalysis [1] and chemical sensing applications [2]. For most of the applications some kind of modification of CNT is required. Non‐covalent modification can be performed without disrupting the structure of both single wall (SWCNT) and multi walled CNT (MWCNT). Covalent modification of SWCNT can lead to a loss of advanced properties like electric conductivity because of the structural changes [3], while properties of MWCNT are not affected by this modification. Here we present a new covalent modification of pristine MWCNT by quaternary ammonium groups and their characterization. The quaternary ammonium groups have been introduced in a multi‐step reaction. The first step was nitrification which was performed by treatment of MWCNT with the mixture of concentrated HNO3 and H2SO4 in the 9:10 volume ratio at 60 °C and for 3 hours. The nitro groups were reduced to amine groups by Bechamp reduction, by applying Fe powder and hydrochloric acid, in ethanol reflux for 2 hours. After purification of amine‐modified MWCNT, direct quaternization of amine groups was performed with the application of CH3I, in dimethylformamide at room temperature. The modification steps were followed with FTIR and 13C and H NMR characterization.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



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Citiraj ovu publikaciju

Ravnjak, Gabriela; Dandić, Andrea; Budetić, Mateja; Samardžić, Mirela; Sečenji, Aleksandar
Covalent modification of MWCNT with quaternary ammonium groups // 26. hrvatski skup kemičara i kemijskih inženjera s međunarodnim sudjelovanjem 4. simpozij Vladimir Prelog Knjiga sažetaka / Galić, Nives ; Rogošić, Marko (ur.).
Zagreb, 2019. str. 58-58 (poster, recenziran, sažetak, znanstveni)
Ravnjak, G., Dandić, A., Budetić, M., Samardžić, M. & Sečenji, A. (2019) Covalent modification of MWCNT with quaternary ammonium groups. U: Galić, N. & Rogošić, M. (ur.)26. hrvatski skup kemičara i kemijskih inženjera s međunarodnim sudjelovanjem 4. simpozij Vladimir Prelog Knjiga sažetaka.
@article{article, year = {2019}, pages = {58-58}, keywords = {multi walled carbon nanotubes, covalent modification, quaternary ammonium groups}, isbn = {978-953-6894-67-3}, title = {Covalent modification of MWCNT with quaternary ammonium groups}, keyword = {multi walled carbon nanotubes, covalent modification, quaternary ammonium groups}, publisherplace = {\v{S}ibenik, Hrvatska} }