From icebergs to geysers: the story behind hydrophobic effect (CROSBI ID 707010)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa
Podaci o odgovornosti
Usenik, Andrea ; Leko, Katarina ; Hanževački, Marko ; Pičuljan, Katarina ; Petrović Peroković, Vesna ; Car, Željka ; Požar, Josip
engleski
From icebergs to geysers: the story behind hydrophobic effect
The temperature and solvent effect on the complexation of various guests (Figure 1) with α-, β- and γ-cyclodextrin and cucurbit[7]uril was explored experimentally and by means of molecular dynamics simulations. The stability constants of all investigated complexes were by far the highest with cucurbit[7]uril in water. A pronounced temperature dependence of ΔrH° and ΔrS°, resulting in almost complete enthalpy-entropy compensation was observed for most explored host-guest systems. For those systems complexation thermodynamics was in line with the classical rationale of the hydrophobic effect at lower temperatures, and the non-classical explanation at higher ones. The optimized inclusion complex structures corresponded to those deduced by means of NMR spectroscopy and the experimentally obtained and calculated ΔrG° were in very good agreement.
hydrophobic effect ; solvophobic effect ; inclusion complex ; complexation thermodynamics ; cyclodextrins ; cucurbit[7]uril ; mannoconjugates
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Podaci o prilogu
93-94.
2021.
objavljeno
Podaci o matičnoj publikaciji
5. Simpozij studenata doktorskih studija PMF-a 2021 : knjiga sažetaka
Barišić, Dajana
Zagreb: Prirodoslovno-matematički fakultet Sveučilišta u Zagrebu
978-953-6076-90-1
Podaci o skupu
5. Simpozij studenata doktorskih studija PMF-a = 5th Faculty of Science PhD Student Symposium
predavanje
24.04.2021-25.04.2021
Zagreb, Hrvatska